Syntheses, structures and magnetic properties of three cobalt(II) coordination polymers based on flexible itaconic acid ligands

Yin, Wei; Jia, Shuang; He, Yong; Li, Guilian; Li, Yun-Ping; Ju, Feng-Yang; Liu, Guang‐Zhen

doi:10.1007/s11243-018-0272-y

Cited by 12 publications

(1 citation statement)

References 32 publications

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“…The flexible ligands with at least one sp 3 -hybrid atom (generally C, N, O or S) in their backbones are often used to synthesize the coordination polymers because the flexible sections can twist or rotate around a single bond to meet the requirements of various metal-ligand coordination fashions. [17][18][19][20] Through the careful analysis of our and other researchers' previous work, it was found that the aliphatic carboxylates ligands (such as itaconic acid [21][22][23][24][25] and citraconic acid [26][27][28][29] ), had better flexibility than those aromatic carboxylic acids (for example, phenylacetate acid [30][31][32][33] and phenylpropionic acid). [34,35] Furthermore, the N-donor ligand is a very important component of adjusting the structures and flexibilities of coordination polymers to satisfy the requirement of coordination geometries of metal ions in the assembly process.…”

Section: Introductionmentioning

confidence: 99%

N‐donor‐induced Two Co(II) Coordination Polymers Derived from the Flexible Citraconic Acid as Photocatalysts for the Decomposition of Organic Dyes

Yin

Liu

et al. 2021

Zeitschrift anorg allge chemie

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Two Co(II) coordination polymers, {[Co(ca)(bpe)(H 2 O)] • H 2 O} n (1) and [Co(ca)(bibp)] n (2) (H 2 ca = citraconic acid, bpe = 1,2-di(4pyridyl)ethylene, bibp = 4,4'-bis(imidazolyl)biphenyl) were prepared by hydrothermal reactions, and characterized by singlecrystal X-ray diffractions, elemental analysis, FT-IR, PXRD and TGA. Compound 1 shows a 2D grid layer containing Cocarboxylate chains. Compound 2 exhibits a three-dimensional metal-organic framework with the dia topology type and 6 6 topology symbol. Both compounds have high thermal stabilities and good phase purity. The photocatalytic reactions of two compounds were investigated under UV irradiation in the presence of H 2 O 2 , and the results show that both compounds are highly efficient photocatalysts for MB and RhB degradation, which may be used as potential materials for wastewater treatment.

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Section: Introductionmentioning

confidence: 99%

N‐donor‐induced Two Co(II) Coordination Polymers Derived from the Flexible Citraconic Acid as Photocatalysts for the Decomposition of Organic Dyes

Yin

Liu

et al. 2021

Zeitschrift anorg allge chemie

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5‐(4′‐carboxylphenoxy) isophthalic acid and 1, 4‐bis(1‐imidazolyl)benzene appended Co(II)‐based MOF as efficient photocatalyst for nitrofurantoin degradation

Wang,

Pu,

et al. 2024

Applied Organom Chemis

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A new Cobalt(II)‐based metal–organic framework (MOF) with composition [Co2(μ2‐OH)(L)(bib)·H2O·2DMA]n (1) (H3L = 5‐[4′‐carboxylphenoxy] isophthalic acid, bib = 1, 4‐bis[1‐imidazolyl]benzene, DMA = dimethylacetamide) has been solvothermally synthesized and characterized. The MOF exhibits unprecedented topology with Schläfli symbol (43)2(4.66.1686) and display optical band gap of 3.68 eV and hence utilized as photocatalyst to photodegrade antibiotics such as metronidazole, tinidazole, nitrofurantoin, and dimetridazole. Among these antibiotics, it displays exceptional photocatalytic degradation of nitrofurantoin. Additional studies suggest that at pH 5 and 5 mg/L dosage of 1, 99.66% of nitrofurantoin decomposes at its 40 ppm concentration. Further, mechanistic pathway for light‐driven nitrofurantoin decomposition has been explored by utilizing experimental, namely, radical trapping experiments and computational techniques employing density of states and Hirshfeld surface analyses.

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Hydrothermal syntheses, crystal structures, and photocatalytic properties of two Co(II) complexes with the flexible citraconic acid

Yin

Liu

et al. 2019

J Chinese Chemical Soc

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Two Co(II) coordination polymers, [Co(ca)(bib)] n (I) and {[Co(ca)(bibp) 1.5 ]Á 1.5H 2 O} n (II) (H 2 ca = citraconic acid, bib = 1,4-bis(1-imidazoly)benzene, bibp = 1,4-bis-[4-(imidazol-1-yl)benzyl]piperazine), were prepared by hydrothermal method and measured structurally by single-crystal X-ray diffraction, infrared spectroscopy, and elemental analysis. Complex I shows a 2D layer structure containing Cocarboxylate chains. Complex II displays a 3D metal-organic framework composed of the binuclear [Co 2 (CO 2 ) 2 ] 2+ cluster nodes through ca 2− and bibp as linkers with (4 12 Á6 3 ) topology. Complexes I and II have high thermal stabilities because their frameworks maintain good integrity before 340 C and 265 C, respectively. Both complexes show well photocatalytic activities for methylene blue degradation under UV irradiation in the presence of H 2 O 2 , which may be used as potential materials for photocatalytic dyes degradation. K E Y W O R D Scitraconic acid, coordination polymer, photocatalytic degradation, thermal stability

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Syntheses, structures and magnetic properties of three cobalt(II) coordination polymers based on flexible itaconic acid ligands

Cited by 12 publications

References 32 publications

N‐donor‐induced Two Co(II) Coordination Polymers Derived from the Flexible Citraconic Acid as Photocatalysts for the Decomposition of Organic Dyes

N‐donor‐induced Two Co(II) Coordination Polymers Derived from the Flexible Citraconic Acid as Photocatalysts for the Decomposition of Organic Dyes

5‐(4′‐carboxylphenoxy) isophthalic acid and 1, 4‐bis(1‐imidazolyl)benzene appended Co(II)‐based MOF as efficient photocatalyst for nitrofurantoin degradation

Hydrothermal syntheses, crystal structures, and photocatalytic properties of two Co(II) complexes with the flexible citraconic acid

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