Syntheses, structures, and reactions of cyrhetrenylphosphines; applications in palladium catalyzed Suzuki cross-coupling reactions

Unsymmetrical cyrhetrenyl and ferrocenyl azines derived from 5-nitrofurane: Synthesis, structural characterization and electrochemistry

“…1 for 1a and Fig. 2 for 2b. In 1a, the cyrhetrenyl group exhibited a typical three-legged piano stool type of structure, which is commonly observed for other half sandwich rhenium (I) complexes [12,18]. The asymmetric unit of the orthorhombic lattice contains two molecules (Z'=2), but only one of these molecules is shown in Fig.…”

Microwave-Assisted Synthesis of Novel Perimidinium Salts as N-Heterocyclic Carbene Precursors: Involvement in Palladium-Catalyzed Cross-Coupling Reactions

“…[4][5][6][7][8][9] For both reactions, choosing of ligand plays an important role for efficacy of catalyst. Various type of ligands were used in the palladium-catalyzed Heck and Suzuki reactions [10][11][12] and one of the most important ligand type is N-heterocyclic carbene (NHC) and the first application of the Pd-NHC-catalyzed Heck reaction was reported by Herrmann. 13 Strong electron-donating ability of NHC ligands give their metal complexes stability to heat, air, and moisture.…”