Synthesis and antibacterial characterization of waterborne polyurethanes with gemini quaternary ammonium salt

Zhang, Yi; Li, Yifan; Li, Jiehua; Gao, Yunlong; Tan, Hong; Wang, Kunjie; Li, Jianshu; Fu, Qiang

doi:10.1007/s11434-015-0811-2

Cited by 61 publications

(48 citation statements)

References 40 publications

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“…The surface activity and antimicrobial activities of their polymers are superior to DTAB. The waterborne polyurethane was also synthesized with gemini quaternary ammonium salt [61]. They dispersed waterborne polyurethane (WPU) in aqueous phase with PSA contained in emulsion.…”

Section: Gemini Antimicrobial Surfactants and Polymersmentioning

confidence: 99%

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Cationic Polymers with Tailored Structures for Rendering Polysaccharide-Based Materials Antimicrobial: An Overview

2019

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Antimicrobial polymers have attracted substantial interest due to high demands on improving the health of human beings via reducing the infection caused by various bacteria. The review presented herein focuses on rendering polysaccharides, mainly cellulosic-based materials and starch to some extent, antimicrobial via incorporating cationic polymers, guanidine-based types in particular. Extensive review on synthetic antimicrobial materials or plastic/textile has been given in the past. However, few review reports have been presented on antimicrobial polysaccharide, cellulosic-based materials, or paper packaging, especially. The current review fills the gap between synthetic materials and natural polysaccharides (cellulose, starch, and cyclodextrin) as substrates or functional additives for different applications. Among various antimicrobial polymers, particular attention in this review is paid to guanidine-based polymers and their derivatives, including copolymers, star polymer, and nanoparticles with core-shell structures. The review has also been extended to gemini surfactants and polymers. Cationic polymers with tailored structures can be incorporated into various products via surface grafting, wet-end addition, blending, or reactive extrusion, effectively addressing the dilemma of improving substrate properties and bacterial growth. Moreover, the pre-commercial trial conducted successfully for making antimicrobial paper packaging has also been addressed.

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Section: Gemini Antimicrobial Surfactants and Polymersmentioning

confidence: 99%

“…He et al [62] further developed a novel surface structure consisting of a contact-active antibacterial upper-layer and an antifouling sub-layer derived from antimicrobial polymer [61]. This structure effectively solved the problem of dead cells blocking the antibacterial surface (Figure 10).…”

Section: Gemini Antimicrobial Surfactants and Polymersmentioning

confidence: 99%

Cationic Polymers with Tailored Structures for Rendering Polysaccharide-Based Materials Antimicrobial: An Overview

2019

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“…In recent years, the study of corrosion inhibition performance using Gemini surfactants is more prevalent (Al-Amiery et al, 2014;Asefi and Mahmoodi, 2010;Cao and Hou, 2016;Du et al, 2018;Hegazy and Abdallah, 2010;Qiu et al, 2008;Qiu and Lv, 2016;Song et al, 2011;Wang et al, 2010;Xia et al, 2015Xia et al, , 2016Zhang et al, 2011Zhang et al, , 2015. Most studies have focused on the corrosion inhibition performance of steel.…”

Section: Introductionmentioning

confidence: 99%

The Preparation of a Novel Corrosion Inhibitor and Its Corrosion Inhibition Behavior on 2024 Al‐Cu‐Mg Alloy in Acid Solution

Jia

Yang

et al. 2019

J Surfact & Detergents

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A new corrosion inhibitor was synthesized from chloroacetyl chloride, 1,3‐propanediamine, and dodecyldimethyl tertiary amine. The structure of the synthesized product was characterized using Fourier transform infrared(FTIR). The critical micelle concentration (CMC) was determined from surface tension measurements. The inhibition behavior of the corrosion inhibitor for 2024 Al‐Cu‐Mg alloy was studied using the weight‐loss method and electrochemical measurements in hydrochloric acid solution. Experimental results show: The CMC is 7.767 × 10−4 mol L−1 and IE (C pro = 1 × 10−3 mol L−1) ≈ 87.9%. The adsorption free energy is calculated to be −33.12 kJ mol−1. Therefore, the adsorption mode is more inclined to physical adsorption. When the concentration of the synthesized product is lower than the CMC, it satisfies the Langmuir adsorption model; when the concentration is higher than the CMC, it no longer follows the Langmuir adsorption model.

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“…Unfortunately, drug toxicity of QAS bearing longer-chain alkyl groups also strengthen as well as benzyl-QAS. Tremendous research efforts have been devoted to development of alternative antibacterial therapeutics that are not easily forming resistance, such as quaternary ammonium salts (QAS), which destruct cell membrane of bacteria and induce the leakage of intracellular components from bacterial cells 16 . Thus, it becomes urgent to design and prepare one kind of novel antibacterial with higher antibacterial activities and lower drug toxicity.…”

Section: Introductionmentioning

confidence: 99%

Synthesis, physiochemical property and antimicrobial activity of novel quaternary ammonium salts

Xie

Cong

Zhao

et al. 2017

Journal of Enzyme Inhibition and Medicinal Chemistry

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Twenty-four novel 5-phenyl-1,3,4-oxadiazole-2-thiol (POT) analogues, benzo[d]oxazole-2-thiol, benzo[d]thiazole-2-thiol and 5-methyl-1,3,4-thiadiazole-2-thiol-substituted N,N-bis(2-hydroxyethyl) quaternary ammonium salts (QAS) (5a-d, 6a-d, 7a-d, 10a-d, 13a-d, 16a-d) were prepared and characterised by FTIR, NMR and elemental analysis. Part of target compounds (5d, 6d, 7d, 10d, 13d, 16d) displayed potent antimicrobial effect against ten common pathogens (S. aureus, α-H-tococcus, β-H-tococcus, E. coli, P. aeruginosa, Proteus vulgaris, Canidia Albicans, Cytospora mandshurica, Physalospora piricola, Aspergillus niger) and had relatively low cytotoxity against two human cell lines (HaCat and LO2). TEM and SEM images of E. coli and S. aureus morphologies treated with 7d showed that the antibacterial mechanism might be the QAS fixing on cell wall surfaces and puncturing to result in the release of bacterial cytoplasm. This study provides new information of QAS, which could be used to design novel antimicrobial agents applied in clinic or agriculture.

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Synthesis and antibacterial characterization of waterborne polyurethanes with gemini quaternary ammonium salt

Cited by 61 publications

References 40 publications

Cationic Polymers with Tailored Structures for Rendering Polysaccharide-Based Materials Antimicrobial: An Overview

Cationic Polymers with Tailored Structures for Rendering Polysaccharide-Based Materials Antimicrobial: An Overview

The Preparation of a Novel Corrosion Inhibitor and Its Corrosion Inhibition Behavior on 2024 Al‐Cu‐Mg Alloy in Acid Solution

Synthesis, physiochemical property and antimicrobial activity of novel quaternary ammonium salts

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