Synthesis and Applications of Borides, Carbides, Phosphides, and Nitrides

Ningthoujam, Raghumani Singh; Joshi, Rashmi

doi:10.1007/978-981-16-1892-5_9

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Cited by 5 publications

References 277 publications

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Classification of Ferrites, Synthesis and Properties of Spinel Ferrite Nanoparticles and Their Applications

Ojha,

Oza,

Agrawal

et al. 2024

Indian Institute of Metals Series

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Classification of Ferrites, Synthesis and Properties of Spinel Ferrite Nanoparticles and Their Applications

Ojha,

Oza,

Agrawal

et al. 2024

Indian Institute of Metals Series

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Applications of Magnetic Materials

Agrawal,

Srivastava,

Ningthoujam

2024

Indian Institute of Metals Series

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Metal nitrides as electrocatalysts in green ammonia synthesis

Januszewska-Kubsik,

Podsiadło,

Pudełko

et al. 2024

Appl. Phys. A

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Green ammonia is assumed to be an important part of the European hydrogen economy and one of the most important substrates of chemical industry. The future development of its manufacturing processes can be related to the electrocatalytic studies yielding in the development of the catalytic materials that would effectively break the nitrogen-nitrogen bond to successfully drive the N2RR—a process of molecular nitrogen electroreduction to ammonia. Molecular nitrogen is characterized with strong triple bond energies (942 kJ/mol) which leading into large dissociation energy of N2 (9,76 eV) and also large energy barrier of the first step of triple bond dissociation 410 kJ/mol (4,25 eV). Those large energies makes reduction to ammonia an extremely difficult task. Metal nitrides of d and f block became in interest due to their activity in ammonia production from molecular nitrogen and hydrogen. Practically all the transition elements occurs in one of the four types of crystalline structures: regular, regular face cantered, hexagonal and hexagonal close packed. The reactions of these metals with nitrogen (or ammonia) typically yields in nitride compounds of an identical type of crystalline structure as the initial metal. Dealing with single metal systems, their ternary counterparts and metal–metal nitride heterostructures, the presented review shows that nitrides are promising groups of electrocatalytic materials. Being property-prone to their internal structural features such as non-stoichiometry and correlated concentration of nitrogen vacancies, metal nitrides are a good candidate for joined investigations spanned between electrochemistry, inorganic chemistry and material engineering.

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Synthesis and Applications of Borides, Carbides, Phosphides, and Nitrides

Cited by 5 publications

References 277 publications

Classification of Ferrites, Synthesis and Properties of Spinel Ferrite Nanoparticles and Their Applications

Classification of Ferrites, Synthesis and Properties of Spinel Ferrite Nanoparticles and Their Applications

Applications of Magnetic Materials

Metal nitrides as electrocatalysts in green ammonia synthesis

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