2023
DOI: 10.2183/pjab.99.025
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Synthesis and applications of helical polymers with dynamic and static memories of helicity

Eiji YASHIMA

Abstract: This review mainly highlights our studies on the synthesis of one-handed helical polymers with a static memory of helicity based on the noncovalent helicity induction with a helical-sense bias and subsequent memory of the helicity approach that we developed during the past decade. Apart from the previous approaches, an excess one-handed helical conformation, once induced by nonracemic molecules, is immediately retained (“memorized”) after the complete removal of the nonracemic molecules, accompanied by a signi… Show more

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Helical polyamines

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et al. 2024
Chem. Sci.