2023
DOI: 10.1002/aoc.7069
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Synthesis and catalytic applications of metal complexes supported by indole‐functionalized mesoionic 1,2,3‐triazolylidenes

Abstract: We report the synthesis and full characterization of a novel series of indole‐derived triazolium salts and their corresponding triazolylidene gold, palladium, rhodium, and iridium complexes. All new compounds were fully characterized by means of 1H and 13C NMR spectroscopy, elemental analyses, and in the case of triazoliums 1 and 2 and complexes 3, 4, and 9, by single crystal X‐ray diffraction. Gold complexes demonstrated a good catalytic performance in the hydrohydrazination of terminal alkynes producing a se… Show more

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