Aluminum metal matrix composites are increasingly popular nowadays because of their wide range of uses. The low weight and excellent mechanical qualities, such as strength and hardness, of Al-Al2O3 composites make them useful in many fields, including automotive, aerospace, electronics, aeronautics, and military. Most of the engine components are made of aluminum-silicon alloys because of their excellent casting and forming properties. In engine components wear is a crucial parameter to be considered therefore in this investigation Al-Si alloy with varying percentages of V2O5 has been considered to develop the Al-Al2O3 composite and evaluate its tribological aspect. For composite development, a novel in-situ approach has been used with the help of the stir-casting method. The tribological behavior of the different composites was examined experimentally and studied with sliding distance, applied load, and the amount of reinforcement. Composites show a significant increase in hardness relative to the base alloy because of the generation of hard alumina particles within the melt. The wear behavior of in-situ Al-Al2O3 composites was studied using a pin-on-disc setup. In terms of COF and wear rate, the composite with a 1% addition of V2O5 performed better in the trial.