Synthesis and Characterisation of the Nitridocuprate(I) Nitride Carbodiimide (Sr₆N)[CuN₂][CN₂]₂

Abstract

The strontium nitridocuprate(I) nitride carbodiimide has been successfully produced and characterised. Single crystals were grown in metal ampoules, utilising an alkali metal as a fluxing agent. Structural characterisation was conducted via single‐crystal X‐ray diffraction and the identity of the [CN2]2– anion as carbodiimide was confirmed by Raman spectroscopy. Diamagnetic behaviour over a large temperature range supports the copper(I) electronic state.

Plasmon Chemistry on Ag Nanostars: Experimental and Theoretical Raman/SERS Study of the Pesticide Thiacloprid Bond Cleavage by the Plasmon Deactivation Effect

“…According to the theoretical calculations, the resulting dihedral angle between TZDr and CIm is of 4.4°, in agreement with the reported data . Then, it is highly probable that a strong resonance between the latter ring could lead to the appearance of a new SERS band ascribed to an asymmetric NCN stretching mode at 1936 cm –1 , consistent with related publications. , …”

“… 67 Then, it is highly probable that a strong resonance between the latter ring could lead to the appearance of a new SERS band ascribed to an asymmetric N=C=N stretching mode at 1936 cm –1 , consistent with related publications. 66 , 68 …”

“…67 Then, it is highly probable that a strong resonance between the latter ring could lead to the appearance of a new SERS band ascribed to an asymmetric N�C�N stretching mode at 1936 cm −1 , consistent with related publications. 66,68 The proposed resonance −S ⊕ �C(N)−N�C�N ⊖ structure is promoted by the interaction of Thia with the metal surface of the AgNSp. On the other hand, this resonance structure is promoted by the lowering of the conformational potential barrier by the metal plasmon.…”

Combining Nitridoborates, Nitrides and Hydrides—Synthesis and Characterization of the Multianionic Sr6N[BN2]2H3

“…[26,[34][35] Firstly, Sr 6 N[BN 2 ] 2 H 3 seems to be structurally related to the compounds (Sr 6 N)[MN 2 ][CN 2 ] 2 (M=Co, Fe, Cu) and M 2 [CN 2 ]Cl 2 (M=Sr, Eu), which feature the same layer-like structure and isoelectronic [NÀ CÀ N] 2À units. [36][37][38][39] But taking a closer look at the network reveals that the coordination polyhedra and orientation of the [CN 2 ] 2À units along the layers vary significantly from those of our [BN 2 ] 3À units. However, the compounds AE 3 BX 2 (AE=Ca or Sr, B=[C 3 ] 4À or [CBN] 4À and X=Cl or Br) show more structural similarities to our title compound Sr 6 N[BN 2 ] 2 H 3 .…”

“…Firstly, Sr 6 N[BN 2 ] 2 H 3 seems to be structurally related to the compounds (Sr 6 N)[ M N 2 ][CN 2 ] 2 ( M =Co, Fe, Cu) and M 2 [CN 2 ]Cl 2 ( M =Sr, Eu), which feature the same layer‐like structure and isoelectronic [N−C−N] 2− units [36–39] . But taking a closer look at the network reveals that the coordination polyhedra and orientation of the [CN 2 ] 2− units along the layers vary significantly from those of our [BN 2 ] 3− units.…”