Synthesis and characteristics of aluminate spinel ceramic pigments based on spent aluminium-cobalt-molybdenum catalyst

Abstract

Purpose The purpose of this paper is to conduct the directed synthesis of blue-colour aluminate spinel pigments based on spent aluminium–cobalt–molybdenum (ACM) catalyst and to study peculiar features of mineral formation processes and changes in their colour indices depending on composition and firing temperature. Design/methodology/approach Aluminate spinel ceramic pigments with specified colour indices were synthesised by directed formation of their mineral composition and identification of the most rational technological parameters of production. Mineral composition of synthesised pigments was evaluated by X-ray phase analysis. The colour indices of pigments and pigment-containing glaze coatings were studied on the comparator colour. The chemical resistance of pigments was determined by loss of their weight loss after boiling in 1 N hydrochloric acid solution and 1 N sodium hydroxide solution. Findings Peculiar features of formation of the mineral composition of aluminate spinel pigments based on the ACM catalyst were studied. The expediency of using magnesium and zinc oxides in their composition has been proved. It is found that for the formation of stable pigments of intense blue colour, a concentration of cobalt (II) oxide in the amount of 0.5 mol is sufficient, which is 23.1 Wt.%. The colour of such pigments is determined by the ratios of cobalt, magnesium and zinc aluminates, which form a spinel solid solution. Practical implications The use of developed aluminate spinel pigments provides obtaining of high-quality glass coatings of blue colour, in particular, for ceramics. Originality/value Aluminium oxide in the spent ACM catalyst is predominantly in the active form (of amorphous aluminium hydroxide and y-Al2O3). This is a prerequisite for the use of this waste material as a complete substitute for chemically pure Al2O3 in the technology of aluminate spinel pigments and reduction of their firing temperature. Besides, spent ACM catalyst already contains 5 Wt.% of expensive cobalt (II) oxide in the form of stable colour-bearing phase CoAl2O4.

A combined DFT and experimental study of NO by NH3-selective catalytic reduction over an Fe-doped CoAl2O4 catalyst

“…19,20 The CoAl 2 O 4 spinel catalysts exhibit a wide range of applications in NH 3 -SCR reactions due to their good catalytic activity, good thermal stability, modulated acid-base properties, structural tunability, and anti-poisoning properties. 14,[21][22][23] However, the pure CoAl 2 O 4 spinel catalysts present some limitations in the NH 3 -SCR reaction, such as high activation energy and relatively low catalytic activity. 24,25 To overcome these limitations and improve the catalytic performance, an effective strategy involves modifying the electronic structure and surface properties of catalysts through doping with transition metals or nonmetallic elements.…”