2014
DOI: 10.3906/kim-1308-19
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Synthesis and characterization of a novel 3-amino-1,2,4-triazole lead(II) coordination polymer

Abstract: A novel [Pb 2(µ -atrz) 2(µ -CH 3 COO)(CH 3 COO)] n (atrz = 3-amino-1,2,4-triazole) complex was synthesized and characterized by IR spectroscopy, thermogravimetric analysis, and single crystal X-ray diffraction. The molecular structure shows that the complex is a coordination polymer in which there are 2 different lead(II) ions with coordination number of 5, Pb(2), and, with a coordination number of 4, Pb(1). Each atrz acts as a bridging ligand between 2 Pb(II) ions through the 2 adjacent nitrogen atoms of the … Show more

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