Synthesis and characterization of AsO[(W,Mo)O3]13, a new (6)-intergrowth tungsten bronze (ITB)

Goudjil, Meriem; Lepore, Giovanni Orazio; Bindi, Luca; Mugnaioli, Enrico; Baroni, Tommaso; Mezaoui, Djillali; Bonazzi, Paola

doi:10.1016/j.jssc.2023.123987

Journal of Solid State Chemistry

2023

DOI: 10.1016/j.jssc.2023.123987

|View full text |Cite

Synthesis and characterization of AsO[(W,Mo)O3]13, a new (6)-intergrowth tungsten bronze (ITB)

Meriem Goudjil

Giovanni Orazio Lepore

Luca Bindi

et al.

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...

Citation Types

Supporting

Mentioning

Contrasting

Year Published

2023

Publication Types

Select...

Article1

Relationship

Self Cite0

Independent1

Authors

Journals

Cited by 1 publication

References 51 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

A new layered potassium-based molybdenum–tungsten monophosphate: synthesis, crystal structure, XPS and magnetic studies

Goudjil,

Lepore,

Bonazzi

et al. 2023

Zeitschrift Für Kristallographie - Crystalline Materials

View full text Add to dashboard Cite

A new compound, K5[(Mo3.2W1.8)O11](PO4)3[(P0.5Mo0.5)O4], was synthesized via solid-state reaction and its crystal structure was determined by single-crystal X-ray diffraction. This compound crystallizes in the space group Pnma, with a = 9.0360(4) Å, b = 10.1603(4) Å, c = 26.1538(12) Å and V = 2401.14(18) Å3. The structure consists of a corner-sharing MO6–TO4 (M = Mo, W; T = P, Mo) polyhedral connection arranged to form an ordered packing of ∼14.9 Å-thick layers parallel to (001). The stacking of the layers forms trigonal, tetragonal and hexagonal channels. XPS study reveals the presence of W at the hexavalent state only, whereas Mo appears as a mixed-valent species (Mo6+, Mo5+ and Mo4+). Magnetic susceptibility reveals the occurrence of a relevant antiferromagnetic coupling and is consistent with the presence of reduced metal species as indicated by the XPS results.

show abstract

A new layered potassium-based molybdenum–tungsten monophosphate: synthesis, crystal structure, XPS and magnetic studies

Goudjil,

Lepore,

Bonazzi

et al. 2023

Zeitschrift Für Kristallographie - Crystalline Materials

View full text Add to dashboard Cite

show abstract

scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.

Contact Info

customersupport@researchsolutions.com

10624 S. Eastern Ave., Ste. A-614

Henderson, NV 89052, USA

This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.

Blog Terms and Conditions API Terms Privacy Policy Contact Cookie Preferences Do Not Sell or Share My Personal Information

Made with 💙 for researchers

Part of the Research Solutions Family.

Synthesis and characterization of AsO[(W,Mo)O3]13, a new (6)-intergrowth tungsten bronze (ITB)

Cited by 1 publication

References 51 publications

A new layered potassium-based molybdenum–tungsten monophosphate: synthesis, crystal structure, XPS and magnetic studies

A new layered potassium-based molybdenum–tungsten monophosphate: synthesis, crystal structure, XPS and magnetic studies

Contact Info

Product

Resources

About