Synthesis and Characterization of Bimetallic Alkoxides of Beryllium and Aluminum

Aggrawal, M.; Mehrotra, R. C.

doi:10.1080/00945718408057518

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2020

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Cited by 11 publications

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“…Various heteronuclear aluminum alcoholates were investigated by Mehrotra and co-workers in several studies. [29][30][31][32][33][34][35][36][37][38][39][40][41][42][43][44][45][46][47][48] Starting from water-free metal chlorides, compounds like [M{Al(OR) 4 ary alcohols [Equation (2)]. [49] For shifting the equilibrium to the product side, the liberated isopropyl alcohol is distilled off.…”

Section: Introductionmentioning

confidence: 99%

Synthesis, Crystal Structures, and Thermolysis Studies of Heteronuclear Transition Metal Aluminum Alcoholates

Küsel

Krautscheid

2020

Zeitschrift anorg allge chemie

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Heteronuclear alcoholate complexes [M{Al(OiPr) 4 } 2 (bipy)] (2-M, M = Fe, Co, Ni, Cu, Zn) and [M{Al(OcHex) 4 } 2 (bipy)] (3-M, M = Fe, Co, Ni, Zn) are formed by adduct formation of [M{Al(OiPr) 4 } 2 ] (1-M, M = Fe, Co, Ni, Cu, Zn) with 2,2Ј-bipyridine and transesterification reaction with cHexOAc. According to crystal structure analyses, in 2-M and 3-M the central transition metal ion M 2+ is coordinated by two chelating Al(OR) 4 moieties and one bipyr

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