Synthesis and characterization of carboxymethyl cellulose (CMC) from salak-fruit seeds as anode binder for lithium-ion battery

Hidayat, Sahrul; Ardiaksa, P; Riveli, Nowo; Rahayu, Iman

doi:10.1088/1742-6596/1080/1/012017

Cited by 24 publications

(11 citation statements)

References 6 publications

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“…In general, there are three main frequency regions observed, and each of these regions is associated with typical group frequencies: 4000–3000 cm − 1 assigned for the O–H stretching, 3000–1750 cm − 1 for the C–H stretching, and 1700–800 cm − 1 for the C═O stretching regions, as earlier reported by Zhuang et al 28 IR fingerprints of these samples proved the present of Li 2 CO 3 on the electrode surface by the broad band of 920–800 cm − 1 and the double peaks at 1520–1380 cm − 1 wavelength. In addition, the absorption peaks at 1520–1380 cm − 1 wavelength of other electrode components could be overlapped the absorption peaks of Li 2 CO 3 and the other components from the anode, such as CMC, … 29 Meanwhile, the broadband of 920–800 cm − 1 in all contacting samples could be overlapped by the others like CMC, SBr, … Moreover, increasing the absorption intensity of these peaks with increasing contact time can confirm this explanation. Herein, it can be observed the absorption peaks of Li 2 CO 3 in the case of the baseline sample.…”

Section: Resultsmentioning

confidence: 63%

Improving the electrochemical performance of lithium‐ion battery using silica/carbon anode through prelithiation techniques

Nguyen Thi,

Le,

Phung

et al. 2023

Battery Energy

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This work focuses on the two most common techniques, including the direct contact method (CM) and the electrochemical method (EM) in the half‐cell applied for the SiO2/C anode. After the prelithiation process, the anodes would be assembled in the coin cells paired with NMC622 cathode. According to electrochemical performance, prelithiation techniques could strengthen the initial discharged capacity and Coulombic efficiency. While the nonprelithiated sample exhibits a poor discharged capacity of 48.43 mAh·g−1 and low Coulombic efficiency of 87.41% in the first cycle, the CM and EM methods illustrated a better battery performance. Specifically, the EM4C exhibited a higher initial discharged capacity and Coulombic efficiency (137.06 mAh·g−1 and 95.82%, respectively) compared to the CM30 (99.08 mAh·g−1 and 93.23%, respectively). As a result, this research hopes to bring some remarkable information to improve full‐cell properties using SiO2/C as an anode material by the prelithiation method.

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Section: Resultsmentioning

confidence: 63%

Improving the electrochemical performance of lithium‐ion battery using silica/carbon anode through prelithiation techniques

Nguyen Thi,

Le,

Phung

et al. 2023

Battery Energy

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“…Peaks at 1 ppm and 3.5 ppm referred to the −CH 3 and −CH 2 − of C 2 H 5 OH undried completely, respectively. The FTIR spectra of ADL powder showed obvious peaks at 1550–1630 cm −1 , corresponding to azo group, whereas the peak at ∼1400 cm −1 can be assigned to the stretching vibrations of the carboxylate group from carboxylic acid salt (Figure a) . Moreover, the Raman spectrum exhibited peaks located at 1400 cm −1 to 1450 cm −1 that can be identified to the integrity of N=N double bond in as‐prepared ADL electrode (Figure b) .…”

Section: Resultsmentioning

confidence: 97%

Azo‐Group‐Containing Organic Compounds as Electrode Materials in Full‐Cell Lithium‐Ion Batteries

et al. 2019

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Inorganic compounds, including graphite, transition metal oxides, and chalcogenides, are widely used as electrode materials in rechargeable lithium-ion batteries (LIBs). However, environmentally friendly and cost-effective alternatives are pursued by focusing on the molecular design of organic materials that could be potential electrode materials in nextgeneration LIBs. Herein, we study the utilization of an organic compound, azobenzene 4,4-dicarboxylate lithium (ADL), as a negative electrode in full-cell LIBs. The full-cell LIBs are assembled by using ADL as the negative electrode, LiCoO 2 (LCO/ADL) or LiFePO 4 (LFP/ADL) as the positive electrode, and 1 M LiPF 6 dissolved in ethylene carbonate/diethylene carbonate (EC : DEC = 1 : 1 by volume) as the electrolyte. Then, ex situ X-ray diffraction (XRD), ex situ X-ray photoelectron spectroscopy (XPS) and scanning electron microscopy (SEM) were carried out to understand the charge storage mechanism and structural changes during the electrochemical reaction. From the charge/ discharge measurements, LFP/ADL rendered a higher specific capacity retention (88.05 %) than LCO/ADL full-cells (73.79 %) after 200 cycles at a current density of 100 mA g À 1 . The XPS analysis revealed that the deposition of metallic Li on the ADL anode in LCO/ADL full-cells led to rapid capacity decay and inferior cyclic performance, whereas Li-free metal deposition had been observed on the ADL anode in LFP/ADL full cells, which explained the higher cyclic stability and capacity retention rate in LFP/ADL full-cells. The present study provides useful insights into the development and practical utilization of organic electrodes in next-generation Li-ion battery technology.

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“…The characteristic absorption peaks of sodium alginate can be seen at 1150 cm −1 (valence vibrations of the C-OH fragment), 1100 cm −1 , 1420 cm −1 (valence symmetric vibrations of the polyanion carboxyl group), 1590–1610 cm −1 (valence antisymmetric vibrations of the polyanion carboxyl group), and 2890–2920 cm −1 , and those of CMC can be seen at 1327 cm −1 (deformation vibrations CH 2 ), 1610–1620 cm −1 (valence vibrations carboxyl group), 2914–2939 cm −1 , and 3427 cm −1 [ 62 , 63 , 64 ].…”

Section: Resultsmentioning

confidence: 99%

Precisely Printable Silk Fibroin/Carboxymethyl Cellulose/Alginate Bioink for 3D Printing

Nashchekina,

Militsina,

Elokhovskiy

et al. 2024

Polymers

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Three-dimensional (3D) bioprinting opens up many possibilities for tissue engineering, thanks to its ability to create a three-dimensional environment for cells like an extracellular matrix. However, the use of natural polymers such as silk fibroin in 3D bioprinting faces obstacles such as having a limited printability due to the low viscosity of such solutions. This study addresses these gaps by developing highly viscous, stable, and biocompatible silk fibroin-based inks. The addition of 2% carboxymethyl cellulose sodium and 1% sodium alginate to an aqueous solution containing 2.5 to 5% silk fibroin significantly improves the printability, stability, and mechanical properties of the printed scaffolds. It has been demonstrated that the more silk fibroin there is in bioinks, the higher their printability. To stabilize silk fibroin scaffolds in an aqueous environment, the printed structures must be treated with methanol or ethanol, ensuring the transition from the silk fibroin’s amorphous phase to beta sheets. The developed bioinks that are based on silk fibroin, alginate, and carboxymethyl cellulose demonstrate an ease of printing and a high printing quality, and have a sufficiently good biocompatibility with respect to mesenchymal stromal cells. The printed scaffolds have satisfactory mechanical characteristics. The resulting 3D-printing bioink composition can be used to create tissue-like structures.

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Synthesis and characterization of carboxymethyl cellulose (CMC) from salak-fruit seeds as anode binder for lithium-ion battery

Cited by 24 publications

References 6 publications

Improving the electrochemical performance of lithium‐ion battery using silica/carbon anode through prelithiation techniques

Improving the electrochemical performance of lithium‐ion battery using silica/carbon anode through prelithiation techniques

Azo‐Group‐Containing Organic Compounds as Electrode Materials in Full‐Cell Lithium‐Ion Batteries

Precisely Printable Silk Fibroin/Carboxymethyl Cellulose/Alginate Bioink for 3D Printing

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