Synthesis and Characterization of Chitosan-Ferrocenylimine Palladacycle and its Catalytic Performance in Heck Reaction

Synthesis, characterization and evaluation of bulky bis(pyrazolyl)palladium complexes in Suzuki–Miyaura cross-coupling reactions

“…[1][2][3][4][5] Most notably, palladium complexes have gained widespread use as catalysts in both industry and academia for performing cross-coupling reactions mainly due to their thermal, oxidative and moisture stability, facile synthesis and the ability to modulate the steric and electronic properties of these palladium complexes. 6 Bisligated palladium complexes, especially those with bulky monodentate ligands are well known for their anticancer properties 7,8 and as effective cross-coupling catalysts. 9,10 Palladium catalysts coordinated in a trans fashion have been reported to demonstrate increased activity for cross-coupling between a wide array of aryl chlorides and amines at low catalyst loading, with a varied substrate scope.…”

“… 1–5 Most notably, palladium complexes have gained widespread use as catalysts in both industry and academia for performing cross-coupling reactions mainly due to their thermal, oxidative and moisture stability, facile synthesis and the ability to modulate the steric and electronic properties of these palladium complexes. 6 Bis-ligated palladium complexes, especially those with bulky monodentate ligands are well known for their anticancer properties 7,8 and as effective cross-coupling catalysts. 9,10 …”