Synthesis and Characterization of Copolymers and Nanocomposites from Limonene, Styrene and Organomodified-Clay Using Ultrasonic Assisted Method

In this work, we report a new facile method for the preparation of myrcene-limonene copolymers and nanocomposites using a Lewis acid as a catalyst (AlCl3) and organo-modified clay as a nano-reinforcing filler. The copolymer (myr-co-lim) was prepared by cationic copolymerization using AlCl3 as a catalyst. The structure of the obtained copolymer is studied and confirmed by Fourier Transform Infrared spectroscopy, Nuclear Magnetic Resonance spectroscopy, and Differential Scanning Calorimetry. By improving the dispersion of the matrix polymer in sheets of the organoclay, Maghnite-CTA+ (Mag-CTA+), an Algerian natural organophilic clay, was used to preparenanocomposites of linear copolymer (myr-co-lim). In order to identify and assess their structural, morphological, and thermal properties, the effect of the organoclay, used in varyingamounts (1, 4, 7, and 10% by weight), and the preparation process were investigated. The Mag-CTA+ is an organophylic montmorillonite silicate clay prepared through a direct exchange process in which they were used as green nano-reinforcing filler. The X-ray diffraction of the resulting nanocomposites revealed a considerable alteration in the interlayer spacing of Mag-CTA+. As a result, interlayer expansion and myr-co-lim exfoliation between layers of Mag-CTA+ were observed. Thermogravimetric analysis provided information on the synthesized nanocomposites’ thermal properties. Fourier transform infrared spectroscopy and scanning electronic microscopy, respectively, were used to determine the structure and morphology of the produced nanocomposites (myr-co-lim/Mag). The intercalation of myr-co-lim in the Mag-CTA+ sheets has been supported by the results, and the optimum amount of organoclay needed to create a nanocomposite with high thermal stability is 10% by weight. Finally, a new method for the preparation of copolymer and nanocomposites from myrcene and limonene in a short reaction time was developed.

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“…These findings support those of the XRD analysis. These results are in agreement with those obtained by H Derdar et al [ 51 ].…”

Section: Resultssupporting

confidence: 94%

“… TEM images of Mag-CTA + ( a ) [ 51 ], myr-co-lim/Mag 1% ( b ), myr-co-lim/Mag 7% ( c ), myr-co-lim/Mag 10% ( d ). …”

Section: Figures Schemes and Tablementioning

confidence: 99%

Green Copolymers and Nanocomposites from Myrcene and Limonene Using Algerian Nano-Clay as Nano-Reinforcing Filler

et al. 2022

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“…A glass slide was coated with a few drops of the dispersed nano-catalyst, which was then dried for 2-3 min at 60 C on a hotplate. Using a gold sputtering machine, a carbon tape stub was used to mount the dried sample on the glass slide and apply a thin layer of gold coating (Derdar et al, 2022).…”

Section: Clay Catalyst Ft-ir Characterizationmentioning

confidence: 99%

Chromatographic assessment of biodiesel production from Peganum harmala seed oil using environmentally benign nano‐catalysts

Alhomaidi,

Aljabri,

Alsharari

et al. 2023

Biomedical Chromatography

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This work gives a comprehensive chromatographic assessment of biodiesel generation from plant seed oil using ecologically friendly nano‐catalysts. Researchers all over the world are actively looking for new ways to satisfy the urgent need for clean and renewable energy sources. The resultant biodiesel was fully characterized utilizing modern techniques like scanning electron microscopy, energy diffraction X‐ray and X‐ray diffraction. The biodiesel gas chromatography/mass spectrometry analysis revealed four significant peaks of fatty acid methyl esters, indicating high‐quality biodiesel production. Furthermore, the biodiesel fuel qualities were discovered to be comparable with international standards such as ASTM D‐6571 and EN‐14214. This indicates that the iron‐modified clay nano‐catalyst can be used as a catalyst for large‐scale biodiesel production. This work is important because it could lead to the large‐scale production of a novel, non‐food feedstock. We may lessen our reliance on fossil fuels and contribute to a more sustainable and ecologically friendly energy future by leveraging the usage of biodiesel produced in this way. The chromatographic assessment of biodiesel production from non‐edible seed oil using environmentally benign nano‐catalysts holds significant promise in advancing sustainable and eco‐friendly biodiesel production methods, contributing to a cleaner and more environmentally responsible energy sector.

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“…As a result, the scattered clay particles transformed into a compact clay particle spatial structure system. The polymer not only adsorbed onto the surface layer of clay but also plugged clay with filiform linkages [40,41]. Consequently, the aqueous polymer solidified, clustering the clay particles and strengthening the chemical bonds established by the clay-polymer interaction.…”

Section: Micro-structural Analysismentioning

confidence: 99%

Response of High Swelling Montmorillonite Clays with Aqueous Polymer

Panda

Bahrami

Nagaraju³

et al. 2023

Minerals

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Expansive clays containing mineral montmorillonite exhibit swelling and shrinkage due to variations in the moisture content, leading to significant distresses. There has been a growing interest in chemical and polymer additives treated for high swelling montmorillonite clays in recent years. However, limited attention has been paid to the effect of polyacrylamide on the soil’s swelling behavior. Moreover, nontraditional methods of the soil treatment are applied for the rapid stabilization of soil. In this article, polyacrylamide polymer is used as an additive to expansive clay to control the swelling phenomenon. Three different percentages—2.5%, 5%, and 7.5%—of polymer are blended with oven-dried soil to determine Atterberg limits, compaction features, and swelling characteristics. Additionally, electrical impedance measurement is conducted on treated soil samples with different moisture contents. The electrical resistance of soils and polymer-treated soils is measured based on the electrical resistivity correlation of soils. Tests results for soils stabilized with polyacrylamide show that swelling is significantly reduced with increasing the additive content. Moreover, the addition of polymer improves resistivity of soil. Aqueous polyacrylamide can be utilized as an effective stabilization additive to enhance properties of expansive clays.

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Synthesis and Characterization of Copolymers and Nanocomposites from Limonene, Styrene and Organomodified-Clay Using Ultrasonic Assisted Method

Cited by 6 publications

References 54 publications

Green Copolymers and Nanocomposites from Myrcene and Limonene Using Algerian Nano-Clay as Nano-Reinforcing Filler

Green Copolymers and Nanocomposites from Myrcene and Limonene Using Algerian Nano-Clay as Nano-Reinforcing Filler

Chromatographic assessment of biodiesel production from Peganum harmala seed oil using environmentally benign nano‐catalysts

Response of High Swelling Montmorillonite Clays with Aqueous Polymer

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