Synthesis and Characterization of Copper(II), Nickel(II), and Cobalt(II) Chelates with Tridentate Schiff Base Ligands Derived from 4-Amino-5-hydroxynaphthalene-2,-7-disulfonic Acid

Tunçel, Mehmet; Serın, Selahattın

doi:10.1081/sim-120021932

Cited by 17 publications

(13 citation statements)

References 19 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…A large number of the Schiff bases and their complexes have been studied in the past because of their wide application and interesting and important properties [3][4][5]. Metal complexes of the Schiff bases derived from substituted salicylaldehydes and various amines have been widely investigated [4,5]. They can serve as models of biologically important species and find applications in biomimetic catalytic reactions, materials chemistry, and industry [5][6][7].…”

mentioning

confidence: 99%

mentioning

confidence: 99%

“…Metal complexes of the Schiff bases derived from substituted salicylaldehydes and various amines have been widely investigated [4,5]. They can serve as models of biologically important species and find applications in biomimetic catalytic reactions, materials chemistry, and industry [5][6][7].…”

mentioning

confidence: 99%

See 2 more Smart Citations

Studies on Mononuclear Chelates Derived from Substituted Schiff Base Ligands: Synthesis and Characterization of a New 5-Methoxysalicyliden-p-Aminoacetophenoneoxime and Its Complexes with Co(II), Ni(II), Cu(II), and Zn(II)

Canpolat

Kaya

2005

Russ J Coord Chem

View full text Add to dashboard Cite

New complexes of Co(II), Ni(II), Cu(II), and Zn(II) with new Schiff bases derived by the condensation of p -aminoacetophenoneoxime with 5-methoxysalicylaldehyde are synthesized. The compounds are characterized by elemental analyses, magnetic susceptibility measurements, IR, 1 H and 13 C NMR spectra, electronic spectral data, and molar conductivity. The thermal stabilities of the compounds are also reported. The Schiff base acts as bidentate O,N-donor atoms, and their metal complexes are supposed to possess a tetrahedral geometry with respect to the central metal ion. The general formula of the 5-methoxysalicyliden-p -aminoacetophenoneoxime Co(II), Ni(II), Cu(II), and Zn(II) complexes is Co(L) 2 , Ni(L) 2 , Cu(L) 2 , and Zn(L) 2 .

show abstract

mentioning

confidence: 99%

mentioning

confidence: 99%

See 1 more Smart Citation

Studies on Mononuclear Chelates Derived from Substituted Schiff Base Ligands: Synthesis and Characterization of a New 5-Methoxysalicyliden-p-Aminoacetophenoneoxime and Its Complexes with Co(II), Ni(II), Cu(II), and Zn(II)

Canpolat

Kaya

2005

Russ J Coord Chem

View full text Add to dashboard Cite

show abstract

“…The solution of (1) (0.345 g, 0.001 mol) in absolute EtOH 5 cm 3 or (0.340 g, 0.001 mol) (2) was added dropwise to a solution of (0.275 g, 0.001 mol) of (A) in 15 cm 3 …”

Section: Schiff Base Ligands (L 1 H and L 2 H)mentioning

confidence: 99%

“…Metal complexes of Schiff bases derived from substituted salicylaldehydes and various amines have been widely investigated [2,3] because of their wide applicability [2][3][4][5][6][7][8][9]. Chelating ligands containing O and N donor atoms show broad biological activity and are of special interest because of the variety of ways in which they are bonded to metal ions [10].…”

Section: Introductionmentioning

confidence: 99%

Synthesis and Characterization of Two New Schiff Base Ligands and their Complexes with Cobalt(II), Nickel(II) and Copper(II)

Yazicı

Akgün

2006

Transition Met Chem

View full text Add to dashboard Cite

Two Schiff base ligands, 2-fE-[(5-phenyl-6H-1,3,4-thiadiazin-2yl)imino]methyneg-1-naphthol (L 1 H) and 5-nitro-2-f[(5-phenyl-6H-1,3,4-thiadiazin-2-yl)imino]methynegphenol (L 2 H) have been prepared from 5-phenyl-6H-1,3,4-thiadiazin-2-amine ðAÞ, 2-hydroxynaphthaldehyde (1) and 2-hydroxy-5-nitrobenzaldehyde (2) Mononuclear Co(II), Ni II and Cu II complexes of the ligands have been prepared by using Co II , Ni II and Cu II salts with a 1:2 metal:ligand ratio. It was determined that the bidentate behavior of the ligands is accomplished via the phenolic oxygen and the azomethine nitrogen atoms. The structures of the ligands and their complexes were identified by using elemental analyses, i.r., 1 H-n.m.r. spectra, electronic spectra, magnetic susceptibility measurements and thermogravimetric analyses (t.g.a.).

show abstract

Structural characterization of disperse black 9 based Cu (II) complex and investigation of its some properties

Tümer¹,

Köse²,

Akar³

et al. 2019

Applied Organom Chemis

View full text Add to dashboard Cite

We obtained the azo‐imine ligand (2,2′‐[4‐(5‐methoxy salicylidene‐4‐iminophenylazo)phenylimino]diethanol) (HL) and its Cu (II) complex (CuL) from the ethanol solution. The complex Cu(L)2 was obtained as single crystals from the CH3OH solution and structurally characterized. The electronic and photoluminescence properties of the ligand and its Cu (II) complex were investigated both in DMF solution and solid state. The oxidation and reduction behaviours of the compounds were studied in the solution and found that the redox processes are irreversible. Thermal studies show that the ligand has higher thermal stability than the CuL complex. Single crystals of the complex were obtained from slow evaporation of a DMF solution of the complex. Crystals of the complex showed a diffraction pattern; however, the structure of the complex was able to be solved.

show abstract

Synthesis and Characterization of Copper(II), Nickel(II), and Cobalt(II) Chelates with Tridentate Schiff Base Ligands Derived from 4-Amino-5-hydroxynaphthalene-2,-7-disulfonic Acid

Cited by 17 publications

References 19 publications

Studies on Mononuclear Chelates Derived from Substituted Schiff Base Ligands: Synthesis and Characterization of a New 5-Methoxysalicyliden-p-Aminoacetophenoneoxime and Its Complexes with Co(II), Ni(II), Cu(II), and Zn(II)

Studies on Mononuclear Chelates Derived from Substituted Schiff Base Ligands: Synthesis and Characterization of a New 5-Methoxysalicyliden-p-Aminoacetophenoneoxime and Its Complexes with Co(II), Ni(II), Cu(II), and Zn(II)

Synthesis and Characterization of Two New Schiff Base Ligands and their Complexes with Cobalt(II), Nickel(II) and Copper(II)

Structural characterization of disperse black 9 based Cu (II) complex and investigation of its some properties

Contact Info

Product

Resources

About