ZnS nanobelts with large aspect ratio are successfully synthesized on a large scale through thermally evaporating of ZnS powder with a trace of SnO 1,* 2 powder using gold coated Si wafer as the substrate at 1100qC. The results indicate that the as-obtained ZnS nanobelts are about 10 nm in thickness and hundreds of micrometers in length, and the aspect ratio reaches more than 10 4 Keywords: Semiconductor; ZnS; Nanobelts; Cathodoluminescence . Substrate dependent experiments are conducted to better study the growth mechanism of the ZnS nanobelts. Subsequently, optical properties of the as-synthesized ZnS nanobelts are also investigated by using a cathodoluminescence (CL) system, which shows the existence of a strong ultraviolet emission at 342 nm and two poor emission peaks at 522 nm and 683 nm at room temperature, respectively. Herein, we successfully fabricated ZnS nanobelts with large aspect ratio by adjusting the substrate types and the evaporation rate, and studied the CL properties of the as-obtained products.ZnS nanobelts reported here are good candidates for optical and optoelectronic devices.ZnS nanobelts with large aspect ratio were synthesized through a thermal evaporation process in a horizontal tube furnace with Au catalyst on Si substrate. A Si wafer (1 cm in length and 5 mm in width) was placed downstream, which is 20 cm away from the source material. 1 g commercial-grade ZnS powder with 0.2 g SnO 2 was placed in the center of a