Synthesis and Characterization of High Temperature Properties of YBa2Cu3O6+δ Superconductor as Potential Cathode for Intermediate Temperature Solid Oxide Fuel Cells

Abstract

YBa2Cu3O6+δ (YBC) oxygen deficient perovskite was synthesized by an auto-combustion method and was studied as potential cathode for Intermediate Temperature Solid Oxide Fuel Cell (IT-SOFC). Synchrotron X-ray thermodiffraction in air shows a phase transition from orthorhombic Pmmm to tetragonal P4/mmm space groups at ~ 425 °C. The chemical compatibility with Ce0.9Gd0.1O1.95 (GDC) electrolyte was investigated in air where certain reactivity was observed above 800 °C. However, the main phase is Ba(Ce1-xYx)O3, a good ionic conductor. The catalytic performance in air was obtained by electrochemical impedance spectroscopy (EIS) measurements on YBC/GDC/YBC symmetrical cells. The area specific resistance (ASR) values change from 13.66 to 0.14 Ω cm2 between 500 and 800 °C, with activation energy (Ea) of 0.41 eV. The results suggest potential applications of YBC as IT-SOFC cathode.

Influence of the Thermal Processing and Doping on LaMnO3 and La0.8A0.2MnO3 (A = Ca, Sr, Ba) Perovskites Prepared by Auto-Combustion for Removal of VOCs

“…LaMnO 3 and La 0.8 A 0.2 MnO 3 (A = Ca, Sr, Ba), perovskites were synthesized via an auto-combustion route, using ethylenediaminetetraacetic acid (EDTA) as organic fuel and chelating agent, and ammonium nitrate as combustion promoter. The selected method, already used for the preparation of other perovskite oxides [37,[50][51][52] has been modified to obtain the desired material in one step directly from the initial dissolution of metals in stoichiometric proportion. This method is cheap, fast (3-5 h total from weighing the reactants to the obtainment of the final sample), and scalable, since it allows us to obtain several grams (5-20 g) of the final material in one beaker.…”