2010
DOI: 10.1016/j.talanta.2010.01.060
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Synthesis and characterization of monoazathiacrown ethers as ionophores for polymeric membrane silver-selective electrodes

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Cited by 18 publications
(11 citation statements)
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“…The favorite donor binding site atom based on the hard-soft acid base (HSAB) concep t is still the primary factor, [1] so the most of the reported heavy metal ionophores for use in ion selective electrodes (ISEs) possess sulfur and/or nitrogen ato ms. [2] Among the heavy metal io ns, Ag + has attracted the interest of researchers, and many compo unds have been used to construct Ag + -ISEs. [2][3][4] Among these compounds, crown ethers show strong ability to form remarkably stable and selective complexes with heavy metal ions and have been found to exhibit interesting host-g uest complexatio n characteristics. [3] Especially, crown ethers containing nitrogen and sulfur donor atoms are of interest as they exhibit high affinities towards Ag + .…”
Section: Introductionmentioning
confidence: 99%
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“…The favorite donor binding site atom based on the hard-soft acid base (HSAB) concep t is still the primary factor, [1] so the most of the reported heavy metal ionophores for use in ion selective electrodes (ISEs) possess sulfur and/or nitrogen ato ms. [2] Among the heavy metal io ns, Ag + has attracted the interest of researchers, and many compo unds have been used to construct Ag + -ISEs. [2][3][4] Among these compounds, crown ethers show strong ability to form remarkably stable and selective complexes with heavy metal ions and have been found to exhibit interesting host-g uest complexatio n characteristics. [3] Especially, crown ethers containing nitrogen and sulfur donor atoms are of interest as they exhibit high affinities towards Ag + .…”
Section: Introductionmentioning
confidence: 99%
“…[2][3][4] Among these compounds, crown ethers show strong ability to form remarkably stable and selective complexes with heavy metal ions and have been found to exhibit interesting host-g uest complexatio n characteristics. [3] Especially, crown ethers containing nitrogen and sulfur donor atoms are of interest as they exhibit high affinities towards Ag + . [5] During the last decade, considerable attentio n has been devoted to the constructio n of Ag + -selective electrodes with mixed-do nor crown ethers as ionophores.…”
Section: Introductionmentioning
confidence: 99%
“…By comparing with other traditional Ag + detection methods, such as atomic absorption, plasma emission spectroscopy, anodic stripping voltammetry and potentiometry, etc, [8][9][10] optical probing for Ag + displayed some attractive advantages, such as good selectivity, low detection limit, convenience in sample preparation and relative low-cost of related equipments. [11][12][13] Despite of the available advances Ag + optical probes have been achieved, two main obstacles are still laying before the further application and improvement of these probes.…”
Section: Introductionmentioning
confidence: 99%
“…Although 2, 2 0 -thiodiethanethiol and its derivatives exhibited excellent selectivity toward Ag þ ions as an ion-selective electrode (J. Zhang et al 2010), according to a literature survey, no preconcentration study has been performed using thiodiethanethiol modified silica coated magnetic nanoparticles for determination of metal ions.…”
Section: Introductionmentioning
confidence: 99%