ABSTRACT. Sintered ceramics of Lu 2 O 3 :Pr,Hf storage phosphor were prepared and their spectroscopic properties were evaluated. It was shown that during irradiation with X-rays as well as with short UV radiation, the material was able to accumulate energy, which could thereafter 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 2 complex mechanism of the process. The fading measured nine months after the material irradiation revealed only about 30% loss of the thermoluminescence intensity. Controlled thermal annealing at defined temperatures as well as optical stimulation with infrared (980 nm, 780 nm) or violet photons (400 nm) proved that it is possible to recover the stored energy either from all traps simultaneously or just from a fraction of them leaving energy stored in the others unaffected. Irradiation with X-rays altered absorption spectrum inducing a new broad band component covering near-UV-blue-green region which perfectly harmonized with a significant decrease of absorption efficiency in the short-UV wavelengths range of f→d Pr 3+ transitions.These variations were fully reversible by means of thermal or UV (400 nm) bleaching. Defects responsible for the energy storing were identified. Long term energy storing traps giving the high temperature TL components were assigned to the presence of Hf(IV) (electron trap), which replaced Lu(III) in the host (TL around 250 °C) and Pr 3+ activator trapping a hole (TL around 340 °C). The good long term stability of the thermoluminescence signal and high efficiency of absorption of ionizing radiation due to a very high density of the lutetia host may make the Lu 2 O 3 :Pr,Hf composition an interesting material for high energy particles dosimetry.