Synthesis and characterization of new pentafluorophenylbismuth(V) derivatives

Naumann, Dieter; Tyrra, Wieland; Lewe, Tobias

doi:10.1016/s0022-1139(97)00034-1

Cited by 6 publications

(2 citation statements)

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“…Despite the increased interest in bismuth triflate as an effective and "green" catalyst in organic chemistry 15 the chemistry of bismuth sulfonates is not well established, though recently bismuth triflate was shown to crystallise as a hexanuclear oxido cluster [Bi 6 O 4 (OH) 4 (OTf ) 6 ](H 2 O). 16 Arenesulfonate complexes of Bi(V) with a variety of substitutions have been studied by Sharutin, 17 Naumann 18 and Barton. 19…”

Section: Introductionmentioning

confidence: 99%

Remarkable in vitro bactericidal activity of bismuth(iii) sulfonates against Helicobacter pylori

et al. 2012

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Section: Introductionmentioning

confidence: 99%

Remarkable in vitro bactericidal activity of bismuth(iii) sulfonates against Helicobacter pylori

et al. 2012

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“…However, these compounds were instable because of their weakly coordinating (less nucleophilic) anions. It was reported that fluorine-containing bismuth compounds such as pentafluorophenylbismuth(V) derivatives [ 46 ] were strong arylating reagents. It is worth mention that fluorotetraphenylbismuth ( 14 ) was the first synthesized thermally stable example, taking advantage of its unique amphiphilic property of possessing both nucleophilic (fluorine atom) and electrophilic (phenyl group) moieties on the central bismuth [ 47 ].…”

Section: Synthesis and Property Characterization Of Various Organomentioning

confidence: 99%

Synthesis, Properties Characterization and Applications of Various Organobismuth Compounds

Luan

Zhang²,

Hu³

2011

Molecules

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Organobismuth chemistry was emphasized in this review article due to the low price, low toxicity and low radioactivity characteristics of bismuth. As an environmentally-friendly class of organometallic compounds, different types of organobismuth compounds have been used in organic synthesis, catalysis, materials, etc. The synthesis and property characterization of many organobismuth compounds had been summarized. This review article also presented a survey of various applications of organobismuth compounds in organic transformations, as reagents or catalysts. The reactivity, reaction pathways and mechanisms of reactions with organobismuths were discussed. Less common and limiting aspects of organobismuth compounds were also briefly mentioned.

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Bismuth: Organometallic Chemistry

Whitmire

2005

Encyclopedia of Inorganic Chemistry

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Bismuth readily forms a variety of tri‐ and pentavalent organic derivatives by the reactions of bismuth halides with Grignard, organolithium, organozinc, or organoaluminum reagents. Bismuth(III) triaryl compounds are readily oxidized by chlorine and bromine to triaryl dihalides, while iodine reacts to produce aryl bismuth iodides. Some organobismuth compounds are Lewis acidic, showing the ready formation of higher coordination number adducts with traditional ligands. A variety of organobismuth compounds with bismuth–bismuth and bismuth–transition metal bonds are described. Organobismuth(V) have found uses as selective oxidants and aryl transfer reagents.

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Synthesis and characterization of new pentafluorophenylbismuth(V) derivatives

Cited by 6 publications

References 26 publications

Remarkable in vitro bactericidal activity of bismuth(iii) sulfonates against Helicobacter pylori

Remarkable in vitro bactericidal activity of bismuth(iii) sulfonates against Helicobacter pylori

Synthesis, Properties Characterization and Applications of Various Organobismuth Compounds

Bismuth: Organometallic Chemistry

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