Nanocrystalline Ni 0.85 Se was synthesized by a hydrothermal method. X-ray diffraction analysis by Rietveld method indicated that Ni 0.85 Se has a NiAs-type hexagonal structure. Narrow crystallite size distribution with an average areaweighted size of 〈ɛ F 〉 = 8.5 nm is obtained by Warren-Averbach method. Structural analysis revealed deformed Se atoms octahedron with the shortest distance between Se atoms in adjacent planes 〈Se-Se〉 adj smaller than between nearest neighbors in layer plane 〈Se-Se〉 nea , and a rather short interatomic distance between the transition metal atoms 〈Ni-Ni〉. The optical property of Ni 0.85 Se was studied by UV-spectroscopy. Magnetic measurement shows a ferromagnetic phase transition for Ni 0.85 Se below 14 K.
K E Y W O R D Schalcogenides, magnetic properties, microstructure, nanostructures, UV