Synthesis and characterization of novel eleven-vertex dimetallaheteroborane clusters containing Heavier group 16 elements

Ponniah, S. Joseph; Bharathan, Jeneena K.; Bose, Shubhankar Kumar; Ghosh, Sundargopal

doi:10.1016/j.jorganchem.2012.04.011

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Chemistry of Triple‐Decker Sandwich Complexes Containing Four‐Membered Open B₂E₂ Rings (E = S or Se)

et al. 2018

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Building upon our earlier studies of cobaltaheteroboranes, we explore the chemistry with heavier group 9 metals. Reaction of [Cp*M(μ-Cl)Cl x ] 2 (Cp* = η 5 -C 5 Me 5 ; M = Co, x = 0; M = Rh or Ir, x = 1) with [LiBH 4 ·THF], followed by thermolysis with an excess of chalcogen powders (S or Se), affords dimetallaheteroboranes nido-[(Cp*M) 2 B 2 H 2 E 2 ], 1-4 (1: E = S; 2: E = Se, M = Co; 3 and 4: E = Se, M = Rh and Ir, respectively) in moderate-to-good yields. The solid-state structures of these compounds show open-cage triple-decker clusters. Attempts to isolate the Te analogue have failed; however, in the case of cobalt, we have isolated an 11 skeletal-electron-pair nido-[(Cp*Co) 2 B 5 H 5 Te 2 ], 5. The X-ray diffraction structure of 5 shows monocapped square antiprismatic geometry, with two Te atoms in the core. To close the central four-membered B 2 E 2 open ring [a]

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Chemistry of Triple‐Decker Sandwich Complexes Containing Four‐Membered Open B₂E₂ Rings (E = S or Se)

et al. 2018

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Cyclic and Non-Cyclic Pi Complexes of Molybdenum

Wang

Zhai

Hou

2022

Comprehensive Organometallic Chemistry IV

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Polyhedral Metallaboranes and Metallacarboranes

Kar

Pradhan

Ghosh

2022

Comprehensive Organometallic Chemistry IV

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Synthesis and characterization of novel eleven-vertex dimetallaheteroborane clusters containing Heavier group 16 elements

Cited by 3 publications

References 58 publications

Chemistry of Triple‐Decker Sandwich Complexes Containing Four‐Membered Open B₂E₂ Rings (E = S or Se)

Chemistry of Triple‐Decker Sandwich Complexes Containing Four‐Membered Open B₂E₂ Rings (E = S or Se)

Cyclic and Non-Cyclic Pi Complexes of Molybdenum

Polyhedral Metallaboranes and Metallacarboranes

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Synthesis and characterization of novel eleven-vertex dimetallaheteroborane clusters containing Heavier group 16 elements

Cited by 3 publications

References 58 publications

Chemistry of Triple‐Decker Sandwich Complexes Containing Four‐Membered Open B2E2 Rings (E = S or Se)

Chemistry of Triple‐Decker Sandwich Complexes Containing Four‐Membered Open B2E2 Rings (E = S or Se)

Cyclic and Non-Cyclic Pi Complexes of Molybdenum

Polyhedral Metallaboranes and Metallacarboranes

Contact Info

Product

Resources

About

Chemistry of Triple‐Decker Sandwich Complexes Containing Four‐Membered Open B₂E₂ Rings (E = S or Se)

Chemistry of Triple‐Decker Sandwich Complexes Containing Four‐Membered Open B₂E₂ Rings (E = S or Se)