Synthesis and characterization of poly(1,3‐thiazol‐2‐yl‐carbomoyl) methyl methacrylate: Its metal complexes and antimicrobial activity studies

Abstract

Poly(1,3-thiazol-2-yl-carbomoyl) methyl methacrylate [poly(TCMMA)] is prepared in dimethyl sulfoxide using 2,2Ј-azobisisobutyronitrile as an initiator at 60°C. Poly(TCMMA) is characterized by IR and 1 H-NMR spectroscopic techniques. Cadmium(II), copper(II), and nickel(II) chelates of poly(TCMMA) were synthesized. An elemental analysis of the polychelates suggests a metal/ ligand ratio of 1:2. The polychelates are further characterized by IR and magnetic susceptibility measurements. The thermal properties of the polymer and metal chelates are also discussed. The molecular weights of the poly(TCMMA) are determined by the gel permeation chromatography tech-

Synthesis, characterization, and preliminary antimicrobial evaluation of bisphenol‐A formaldehyde resin coordinated with transition metal complexes of ethylenediamine

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Synthesis and Characterization of Novel Methacrylate Monomers Having Pendant Oxime Esters and Their Copolymerization with Styrene

“…Methacrylic polymers find extensive applications in fiber optics, metal complexes, polymeric reagents, and polymeric supports (1)(2)(3)(4)(5). Recent investigations report the use of oxime esters as irreversible acyl transfer agents where the leaving group, the oxime does not participate in the back reaction (6).…”

Synthesis of novel methacrylate‐based nanocomposites containing ZnO via the hydrothermal method and determination of thermal, optical, and biocidal properties

“…In recent years, interest in nanoscale materials has been heightened as a result of advances in synthetic techniques and the ability to characterize materials at the atomic scale. The addition of fillers to thermoplastic and thermoset polymers has reduced the product cost and boosted the material properties compared to pure polymer 1–3 . With the incorporation of additives, the usage areas of polymers has expanded, and consequently, the production of polymer composites with improved thermal, mechanical, and electrical properties has accelerated the studies on this subject 4 …”

“…The addition of fillers to thermoplastic and thermoset polymers has reduced the product cost and boosted the material properties compared to pure polymer. [1][2][3] With the incorporation of additives, the usage areas of polymers has expanded, and consequently, the production of polymer composites with improved thermal, mechanical, and electrical properties has accelerated the studies on this subject. 4 Because of their high surface area, ZnO nanoparticles exhibit high sensitivity to their chemical environment.…”