Synthesis and Characterization of Poly(Aniline-co-o-Aminoaniline)

Yalçınkaya, Süleyman; Çolak, Nureddin

doi:10.1163/156855511x615038

Cited by 20 publications

(10 citation statements)

References 26 publications

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“…Potassium dichromate and N-methyl-2-pyrrolidone (NMP) were obtained from Merck. Ammonia solution, hydrochloric acid (ADWIC) and bentonite clay (Bentonite, Nanomer ® PGV) were purchased from Süd-Chemie AG, Germany relative density = 2.400 g/cm 3 , form: granules, colour: beige, pH 6.0-9.0), purity is 100% w/w.…”

Section: Methodsmentioning

confidence: 99%

“…They can be synthesized by an electrochemical method or chemical oxidative polymerization. [1][2][3][4] The chemical synthesis is usually carried out by oxidative polymerization in aqueous HCl solution by ammonium peroxydisulfate. [5] Among the investigated polymers, polyaniline (PANI), polypyrrole, poly(o-phenylenediamine) (Po-PDA) and poly(aminophenol) (PAP) have recently been paid a lot of attention for their application in biochemistry, biosensor and the immobilization of protein and enzyme.…”

Section: Introductionmentioning

confidence: 99%

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Non-conventional synthesis and antibacterial activity of poly(aniline-co-o-phenylenediamine)/bentonite nanocomposites

Al-Hussaini

Eldars

2013

Designed Monomers and Polymers

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Copolymers of aniline and o-phenylenediamine/hydrophilic bentonite nanocomposites were synthesized by 5:1 M ratios of the respective monomers with different percentages of nanoclay via modified in situ chemical copolymerization. The results were justified by measuring the FT-IR for PANI-o-PDA/bentonite nanocomposites. The thermal stability was studied. PANI-o-PDA/bentonite nanocomposites were thermally more stable than pure polymer. The antibacterial activities of PANI-o-PDA/bentonite nanocomposites towards both Gram-positive and Gram-negative bacteria were investigated.

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Section: Methodsmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Non-conventional synthesis and antibacterial activity of poly(aniline-co-o-phenylenediamine)/bentonite nanocomposites

Al-Hussaini

Eldars

2013

Designed Monomers and Polymers

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“…However, substituted PANI derivatives such as poly(o-toluidine), poly(o-anisidine), poly(anilineco-o-nitroaniline) and poly(aniline-co-o-anisidine) are more soluble than the unsubstituted PANI. [7][8][9] Conjugated polyaminoarenes such as PANI and its derivatives recently attract a great attention as sensor materials because they have a potential technological application in chemical power sources and electrochromic displays. [10] Aminophenols are interesting electrochemical materials since hydroxyl group in the phenyl ring can be oxidized to quinone and quinone can be reduced again.…”

Section: Introductionmentioning

confidence: 99%

Synthesis and characterization of poly(m-aminophenol)-succinat

Dinç

Yalçınkaya

Altuntaş

et al. 2014

Designed Monomers and Polymers

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Poly(m-aminophenol) (PMAP) and poly(m-aminophenol)-succinat compound (PMAP-Suc) containing ester bridge were synthesized in this study. PMAP were synthesized by chemical oxidative polymerization of m-aminophenol (MAP) in HCl medium with ammonium peroxydisulphate (APS) as an initiator at different temperatures. The optimum polymerization conditions (temperature: 25°C, reaction time: 4 h, normalized MAP/APS ratio, k: 0.625 and mol of MAP/mol of APS, r: 0.5) of PMAP were determined. PMAP was esterified in N-methyl pyrrolidone by using solution of succinic acid as cross-linking agent and concentrated sulphuric acid as catalyst under appropriate ambient conditions. The general scheme of esterification and cross-linking reaction for PMAP is proposed. These reactions were also evidenced by spectroscopic, thermal and surface morphology as well as structural characteristics relationship of macromolecules. The structures of PMAP and PMAP-Suc were characterized by solubility test, FTIR, 1 H NMR and 13 C NMR, UV-vis spectroscopy, thermal (TGA-DTA) and SEM analyses.

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“…Various categories of polymers have been extensively used as transducers in electrochemical biosensors to measure and amplify signals [5,6] . Synthetic polymers, conducting polymers (CPs) and conducting polymer-nanocomposite materials have been reported as effective bio-transducers in the development of glucose biosensors.…”

Section: Introductionmentioning

confidence: 99%

Highly Sensitive Glucose Sensing With Multi-Walled Carbon Nanotubes – Polyaniline Composite

Sharma

Kumar

Deep

2012

Polymer-Plastics Technology and Engineering

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Multi-walled carbon nanotubes (MWCNTs) have been carboxylated and then immobilized with glucose oxidase (GOx) by amine coupling through EDC-NHS chemistry. These functionalized MWCNTs have been introduced into polyaniline matrix by electrochemical method. The different involved steps have been characterized with molecular and electronic spectroscopy. Prepared thin films preserved the enzymatic activity of GOx and their average electrical conductivity was measured as 3.78 Â 10 À1 S cm À1 . Observed response time was 5 s and a linear pattern of current vs. concentration was recorded for 0.5-22 mM glucose.

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Synthesis and Characterization of Poly(Aniline-co-o-Aminoaniline)

Cited by 20 publications

References 26 publications

Non-conventional synthesis and antibacterial activity of poly(aniline-co-o-phenylenediamine)/bentonite nanocomposites

Non-conventional synthesis and antibacterial activity of poly(aniline-co-o-phenylenediamine)/bentonite nanocomposites

Synthesis and characterization of poly(m-aminophenol)-succinat

Highly Sensitive Glucose Sensing With Multi-Walled Carbon Nanotubes – Polyaniline Composite

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