Synthesis and Characterization of Polyesteramide Urethane Derived from Melia Azedarach Seed Oil

Ahamad, Sageer; Imran, Ghazala; Ahmad, Sharif; Hasnat, Abul

doi:10.13005/ojc/310271

Cited by 11 publications

(16 citation statements)

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“…The HEJCA undergo polycondensation reaction with phthalic acid to produce JCPEA. The carboxylic end of JCPEA coupled with the B(OH) 3 and produces JCBPEA. The JCBPEA contain hydroxyl groups at terminals and behave as diol and tailored to a series of urethane modified JCBPEA resins by reaction with TDI in different phr.…”

Section: Preparation Of Coatingsmentioning

confidence: 99%

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Urethane-Modified Boron Containing Polyesteramide of Phthalic Acid from Jatropha Curcas Seed Oil

2016

Chem Sci Trans

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Boron containing polyesteramide synthesized from Jatropha curcas seed oil, a renewable, non-edible and abundantly available resource has been found to show improved performances as coating materials. However, curing of the resins at elevated temperature restrict its viability in many service conditions, especially where baking are not possible. With a view towards the use of boron containing polyesteramide derived from Jatropha curcas seed oil and to cure at ambient temperature, toluylene diisocyanate (TDI) was incorporated in the resin in varying proportion to obtain urethane modified boron containing polyesteramide resins. The latter resins were found to cure at room temperature. The effects of amount of TDI on the drying time were also investigated. The synthesized resins characterized by physicochemical and spectral analyses. The film properties of the ambient cured urethane-modified boron containing polyestramides were also studied.

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Section: Preparation Of Coatingsmentioning

confidence: 99%

“…Syntheses of polymers from renewable resources have attracted the attention of academicians and scientist due to the fast depletion of petrochemical stock and inflated prices [1][2][3] . Furthermore, environmental legislations also force to search bio-based alternatives 4,5 .…”

Section: Introductionmentioning

confidence: 99%

Urethane-Modified Boron Containing Polyesteramide of Phthalic Acid from Jatropha Curcas Seed Oil

2016

Chem Sci Trans

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Section: Introductionmentioning

confidence: 99%

“…The seeds of plants contain about 40-wt % triglyceride oil with sufficiently high iodine value, which provide the film formation ability to the synthesized polymers [13,14]. Meagre utilization of Melia azedarach seed oil, especially in the polymer syntheses encourages us to utilize this triglyceride oil in the synthesis of poly(ester-amide) using adipic acid as a dibasic acid [14][15][16].Poly (ester-amide)s of vegetable oil origin are amide modified alkyds and have hybrid properties of both functionalities pendent amide and repeating ester; consequently show better performances than normal alkyds in terms of hardness, water vapor resistance and corrosion resistance [9,12]. In present work efforts have been made to synthesize the poly (ester-amide) resin through poly (condensation) reaction between adipic acid and fatty amide diol of Melia azedarach seed oil obtained by amidation of triglyceride oil with diethanol amine.…”

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confidence: 99%

Synthesis and Characterization of Poly (ester-amide) of Adipic Acid and Fatty Amide of Melia Azedarach Seed Oil – An Eco-friendly Resource

Hasnat¹,

Ahamad²,

Ahmad³

2017

MOCR

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Abstract.Synthesis of polymeric materials from renewable resources has attracted the attention of researcher worldwide as they are not only reducing the dependency on petrochemicals, a finite resource but also friendly to the environment. Synthesis of valuable polymers from non-conventional and non-edible vegetable oils solves the problem of waste disposal as well as bringing down the cost of end products. Melia azedarach seed oil (MASO), a non-traditional, non-edible and abundantly available resource is utilized for the synthesis of poly (ester-amide) (MAPEAA) by the aminolysis with diethanolamine followed by step-growth polymerization with adipic acid. The MAPEAA polymeric resin was characterized by physic-chemical analyses as per standard reported laboratory methods. The structural elucidation of the resin was carried out by spectral analyses. Physicomechanical and chemical/corrosion resistance performances of the resin were also investigated. Keywords:Melia azedarach seed oil, renewable resource, vegetable oil, Poly (ester-amide) IntroductionThere have been potential demands worldwide for replacing petroleum based raw materials with the renewable ones [1][2][3]. This is quite significant from the societal and environmental points of view. Among different renewable resources vegetable oils obtained from seeds of various plants are in the spotlight of the chemical industries as they are the abundantly available in nature and also show low eco-toxicity as well as low-toxicity towards humans [4,5]. Common traditional seed oils such as linseed, sunflower, castor, soybean, coconut are being largely used in the synthesis of polymers like alkyds, epoxies, polyurethanes, interpenetrating polymer networks (IPN)s, poly (ester-amide)s and many others [4,[6][7][8][9][10]. These polymers are extensively used as coatings, adhesives, insulators and biomedical structures. However, among afore mentioned traditional oils some of them possess medicinal values and are edible too [11,12]. Therefore, it is important to explore the gift of the nature and utilize the non-edible and non-conventional seed oils as starting raw materials for the development polymers, which ultimately reduce the demands of conventional vegetable oils. Melia azedarach belongs to the family meliaceae largely cultivated in rural areas due to its valuable wood [13,14]. The seeds of plants contain about 40-wt % triglyceride oil with sufficiently high iodine value, which provide the film formation ability to the synthesized polymers [13,14]. Meagre utilization of Melia azedarach seed oil, especially in the polymer syntheses encourages us to utilize this triglyceride oil in the synthesis of poly(ester-amide) using adipic acid as a dibasic acid [14][15][16].Poly (ester-amide)s of vegetable oil origin are amide modified alkyds and have hybrid properties of both functionalities pendent amide and repeating ester; consequently show better performances than normal alkyds in terms of hardness, water vapor resistance and corrosion resistance [9,12]. In present work eff...

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“…The petrochemicals have been used as primary raw material for the synthesis of commercially important polymers for the last few decades [7][8][9] . In recent years search for alternative feed stock has been stimulated due to the depletion of petroleum reserves on one hand and the increasing demand for petroleum products on the other 10,11 .…”

Section: Introductionmentioning

confidence: 99%

Studies on Alumina Incorporated Polyesteramide Derived from Meliaazedarach Seed Oil

Hasnat¹,

Naseem²,

Ahmad³

2016

Orient. J. Chem

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Polyesteramide resin (MAPEAM) was prepared from N,N-bis(2-hydroxy ethyl) Melia azedarach oil fatty amide (HEMAFA) a precursor of natural renewable resource using polycondensation reaction with maleic acid. With the view to improve the physico-mechenical properties aluminium was incorporated in backbone of the polymer to obtain the alumina incorporated polyesteramide resin of Melia azedarach seed oil (Al-MAPEAM). The physico-chemical analyses and spectroscopic techniques were used for the characterization of Al-MAPEAM polymeric resin. The film properties of the Al-MAPEAM were also investigated in different corrosive environments as per standard reported methods. Studies shows that syntheses of aluminium incorporated polyesteramide using Melia azedarach seed oil as a starting material provides a more practicable utilization to it.

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Synthesis and Characterization of Polyesteramide Urethane Derived from Melia Azedarach Seed Oil

Cited by 11 publications

References 0 publications

Urethane-Modified Boron Containing Polyesteramide of Phthalic Acid from Jatropha Curcas Seed Oil

Urethane-Modified Boron Containing Polyesteramide of Phthalic Acid from Jatropha Curcas Seed Oil

Synthesis and Characterization of Poly (ester-amide) of Adipic Acid and Fatty Amide of Melia Azedarach Seed Oil – An Eco-friendly Resource

Studies on Alumina Incorporated Polyesteramide Derived from Meliaazedarach Seed Oil

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