2017
DOI: 10.1007/s10853-017-1553-0
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Synthesis and characterization of porous platelet-shaped α-Bi2O3 with enhanced photocatalytic activity for 17α-ethynylestradiol

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Cited by 28 publications
(14 citation statements)
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“…After the photocatalytic decomposition of aqueous TCS in the presence of β-Bi 2 O 3 and β-Bi 2 O 3 :Ce samples, the formation of Bi 2 O 2 CO 3 was obtained for doped and undoped β-Bi 2 O 3 samples as a result of photocorrosion (Figure S12). The formation of Bi 2 O 2 CO 3 during photocatalytic degradation of organic pollutants is a known side reaction when bismuth oxide polymorphs such as α-Bi 2 O 3 , , β-Bi 2 O 3 , , and γ-Bi 2 O 3 are used as photocatalysts.…”
Section: Discussionmentioning
confidence: 99%
“…After the photocatalytic decomposition of aqueous TCS in the presence of β-Bi 2 O 3 and β-Bi 2 O 3 :Ce samples, the formation of Bi 2 O 2 CO 3 was obtained for doped and undoped β-Bi 2 O 3 samples as a result of photocorrosion (Figure S12). The formation of Bi 2 O 2 CO 3 during photocatalytic degradation of organic pollutants is a known side reaction when bismuth oxide polymorphs such as α-Bi 2 O 3 , , β-Bi 2 O 3 , , and γ-Bi 2 O 3 are used as photocatalysts.…”
Section: Discussionmentioning
confidence: 99%
“…After the photocatalytic decomposition of aqueous RhB, both γ-Bi 2 O 3 samples ( 1 , 1a ) contain Bi 2 O 2 CO 3 , whereas Bi 12 SiO 20 ( 2 ) remained unchanged (Figure S7). The formation of Bi 2 O 2 CO 3 during photocatalysis is a known side reaction when bismuth­(III) oxides are used as photocatalyst, and the so-called photocorrosion was discussed recently for α- and β-Bi 2 O 3 . , It is assumed that the in situ formed CO 2 during the mineralization of organic pollutants reacts with the bismuth­(III) oxide forming Bi 2 O 2 CO 3 . In the studies of Shi et al, photocorrosion of α-Bi 2 O 3 in the decomposition of 17α-ethynylestradiol in aqueous solution was obtained already after one catalytic cycle .…”
Section: Discussionmentioning
confidence: 99%
“…The formation of Bi 2 O 2 CO 3 during photocatalysis is a known side reaction when bismuth­(III) oxides are used as photocatalyst, and the so-called photocorrosion was discussed recently for α- and β-Bi 2 O 3 . , It is assumed that the in situ formed CO 2 during the mineralization of organic pollutants reacts with the bismuth­(III) oxide forming Bi 2 O 2 CO 3 . In the studies of Shi et al, photocorrosion of α-Bi 2 O 3 in the decomposition of 17α-ethynylestradiol in aqueous solution was obtained already after one catalytic cycle . Eberl et al and Schlesinger et al reported on the photocorrosion of β-Bi 2 O 3 to partially give Bi 2 O 2 CO 3 after several catalytic cycles in the photocatalytic decomposition of phenol and rhodamine B, respectively.…”
Section: Discussionmentioning
confidence: 99%
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“…Nanomaterials derived from TiO 2 have been regarded as promising photocatalysts for hydrogen generation via water splitting and environmental purification since the ground-breaking report by Honda and Fujishima in 1972 [5]. Especially after Carey et al reported the first use of nano-TiO 2 to degrade polychlorobiphenyls under ultraviolet (UV) irradiation in 1976 [6], various metal oxide-based photocatalysts, including TiO 2 [7][8][9][10][11][12], ZnO [13][14][15][16], Bi 2 O 3 [17][18][19], Cu 2 O [20,21], Fe 2 O 3 [22,23], and NiO/Ni(OH) 2 [24,25] have been developed for the photocatalytic degradation of organic dyes and pollutants. However, most of the catalysts were metal-based, which pose a potential risk of secondary pollution to water bodies [26].…”
Section: Introductionmentioning
confidence: 99%