Synthesis and Characterization of Rhenium Phosphinothiolate Complexes. Crystal and Molecular Structures of [HNEt3][Re{P(C6H4S)3}2], [ReOCl{OP(C6H5)2(C6H4S)}{(P(C6H5)2(C6H4S)}], [Re2O5{P(C6H5)2(C6H4S)}2], and [ReOCl{OP(C6H5)2(

Pérez‐Lourido, Paulo; Romero, Jaime; García‐Vázquez, José A.; Sousa, Antonio; Maresca, Kevin P.; Rose, David J.; Zubieta, Jon

doi:10.1021/ic9715299

Cited by 29 publications

(22 citation statements)

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“…Mixed-valence complexes of rhenium are an uncommon and underinvestigated group of compounds. The examples of such complexes include compounds with Re(III,V) [2], Re(V,VII) [3,4], Re(II,III) [5,6], and Re (I,VII) [7][8][9] centres.…”

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confidence: 99%

“…In this paper a novel example of a Re mixed-valence complex ([ReCl 4 (py)(μ-O)Re(py) 4 Cl]·2py) is presented and discussed. Most plausible, although not unambiguous oxidation state assignment is "Re III/IV ".…”

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confidence: 99%

“…The here presented [ReCl 4 (py)(μ-O)Re(py) 4 Cl]·2py complex crystallizes in monoclinic space group P2 1 /c [17][18][19]. The complex was obtained by solvothermal synthesis in a Berghoff autoclave [20] (see [21] for the starting material preparation procedure).…”

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confidence: 99%

“…in palliative treatment of bone metastases [24], similar applications may be expected for the rhenium analogues. The authors reporting the analogous picoline technetium complex [22] did not provide accurate structure parameters, but solved the oxidation state problem in a later report, completing physicochemical properties characterization for [XL 4 Tc-O-TcX 4 L] (X = Cl/Br, L = pyridine, 4-picoline, 3,5-lutidine) complexes. For these complexes, based on ESCA analysis, Tc ions should differ by no more than a single oxidation state.…”

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confidence: 99%

“…The distorted octahedral units "Re III Cl(py) 4 The title complex molecules form layers parallel to the (011) plane, between which disordered pyridine molecules are located in canals extending along [001] (this may explain their mobility). No stacking interactions between any pyridine rings are observed, only weak C-H...π interactions are preferred.…”

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Synthesis and structural characterization of the novel unusual oxido-bridged rhenium complex with Re atoms in two different coordination environments

Kochel

Hołyńska

2010

Inorganic Chemistry Communications

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Synthesis and structural characterization of the novel unusual oxido-bridged rhenium complex with Re atoms in two different coordination environments

Kochel

Hołyńska

2010

Inorganic Chemistry Communications

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PPh(2-C6H4S)2 as a Pincer Ligand in Nickel(II) and Palladium(II) Complexes — X-ray Structure of [Ni{PPh(C6H4S)2}(PPh2Me)], [Pd2(μ-dppe){PPh(C6H4S)2}2] and [Ni{PPh(C6H4S)2}]2

Cerrada

Falvello

Hursthouse

et al. 2002

Eur. J. Inorg. Chem.

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The phosphanylthiol PPh(2-C 6 H 4 SH) 2 reacts with the Ni II and Pd II complexes [MCl 2 L 2 ] in the presence of NaOEt to give the mononuclear derivatives [M{PPh(C 6 H 4 S) 2 }L] [M = Ni, L = PPh 3 (1), PPh 2 Me (2); M = Pd, L = PPh 3 (3)]. The analogous reaction starting with complexes containing bidentate ligands [MX 2 (L-L)] produces different results depending on the ligand used. The complexes [M{PPh(C 6 H 4 S) 2 }(dppm)] [M = Ni (4), Pd (5)], with an unligated phosphorus atom in the diphosphane are obtained with bis(diphenylphosphanyl)methane (dppm), while the dinuclear complexes [M 2 (µ-dppe){PPh(C 6 H 4 S) 2 }] [M = Ni (6), Pd

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Synthesis and Structural Characterization of Cobalt, Nickel and Copper Phosphanylthiolato Complexes

et al. 2010

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Keywords: Cobalt / Nickel / Copper / Electrochemical synthesis / S ligands / Phosphane ligands Neutral cobalt, nickel and copper complexes of a series of phosphanylthiol ligands Ph n P(C 6 H 4 SH-2) 3-n (n = 1, 2) have been synthesized and characterized by IR and NMR ( 1 H and 31 P) spectroscopy, FAB mass spectrometry and X-ray structural analysis. All of the compounds, with the exception of [Co{Ph 2 PC 6 H 4 S-2} 2 ], were synthesized by electrochemical oxidation of the anodic metal (cobalt, nickel or copper) in an acetonitrile solution of the appropriate ligand and a small amount of tetramethylammonium perchlorate as an electro-

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Synthesis and Characterization of Rhenium Phosphinothiolate Complexes. Crystal and Molecular Structures of [HNEt₃][Re{P(C₆H₄S)₃}₂], [ReOCl{OP(C₆H₅)₂(C₆H₄S)}{(P(C₆H₅)₂(C₆H₄S)}], [Re₂O₅{P(C₆H₅)₂(C₆H₄S)}₂], and [ReOCl{OP(C₆H₅)₂(

Abstract: The trinuclear arene Á/ruthenium cluster cations [H 3

Cited by 29 publications

References 63 publications

Synthesis and structural characterization of the novel unusual oxido-bridged rhenium complex with Re atoms in two different coordination environments

Synthesis and structural characterization of the novel unusual oxido-bridged rhenium complex with Re atoms in two different coordination environments

PPh(2-C6H4S)2 as a Pincer Ligand in Nickel(II) and Palladium(II) Complexes — X-ray Structure of [Ni{PPh(C6H4S)2}(PPh2Me)], [Pd2(μ-dppe){PPh(C6H4S)2}2] and [Ni{PPh(C6H4S)2}]2

Synthesis and Structural Characterization of Cobalt, Nickel and Copper Phosphanylthiolato Complexes

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