2004
DOI: 10.1080/00958970410001666170
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Synthesis and Characterization of the products from reaction of Metal Carbonyls [M(CO)6 (M Cr, Mo, W), Re(CO)5Br, Mn(CO)3Cp] with Salicylaldehyde Methanesulfonylhydrazone

Abstract: Five new complexes, [M(CO) 5 (salmsh)] (M ¼ Cr; 1, Mo; 2, W; 3), [Re(CO) 4 Br(salmsh)], 4, and [Mn(CO) 3 (salmsh)], 5, have been synthesized by the photochemical reaction of metal carbonyls with salicylaldehyde methanesulfonylhydrazone (salmsh). The complexes have been characterized by elemental analyses, EI mass spectrometry, FT-IR and 1 H NMR spectroscopy. The spectroscopic studies show that salmsh behaves as a monodentate ligand coordinating via the imine N donor atom in 1-4 and as a tridentate ligand in 5.

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Cited by 27 publications
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