Synthesis and Characterization of the Cationic Porphyrin meso-Tetrakis(2,3,5,6-tetrafluoro-N,N,N-trimethyl-4-aniliniumyl)porphyrin

La, Timothy; Richards, R.; Miskelly, Gordon M.

doi:10.1021/ic00092a023

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Cited by 43 publications

(25 citation statements)

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“…[Fe(TF 4 TMAP)][OTf] 5 was prepared from 5,10,15,20‐tetrakis(pentafluorophenyl)porphine (Frontier) according to the procedure of Miskelly and co‐workers 10a…”

Section: Methodsmentioning

confidence: 99%

Bioinspired Dismutation of Chlorite to Dioxygen and Chloride Catalyzed by a Water‐Soluble Iron Porphyrin

2008

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“…[Fe(TF 4 TMAP)][OTf] 5 was prepared from 5,10,15,20‐tetrakis(pentafluorophenyl)porphine (Frontier) according to the procedure of Miskelly and co‐workers 10a…”

Section: Methodsmentioning

confidence: 99%

Bioinspired Dismutation of Chlorite to Dioxygen and Chloride Catalyzed by a Water‐Soluble Iron Porphyrin

2008

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“…(TAPPF 16 ) 17,18 or they are equipped with neutral hydrophilic groups. None of the corresponding ionic Ni-porphyrins provides the required electronic environment for a CISSS (Fig.…”

mentioning

confidence: 99%

Coordination-Induced Spin-State-Switch (CISSS) in water

et al. 2014

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We present a non-ionic water-soluble porphyrin that does not exhibit measurable aggregation even at high concentrations in water. The spin state of the corresponding nickel(II) complex changes from completely diamagnetic (low-spin) to paramagnetic (high-spin) upon addition of a strong axial ligand. This leads to a strongly reduced NMR relaxation time of the water protons even at low concentrations of the complex.

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“…(TF 4 DMAP)H 2 or (T( p ‐Me 2 N)F 4 PP)H 2 was synthesized following a literature procedure 18. The complexes [Mn(TF 4 DMAP)] and [Mn(TF 4 TMAP)] were prepared according to modified literature methods for their iron counterparts as detailed below 19. The anion for [Mn(TF 4 TMAP)] was triflate.…”

Section: Methodsmentioning

confidence: 99%

Chlorite Dismutation to Chlorine Dioxide Catalyzed by a Water‐Soluble Manganese Porphyrin

et al. 2010

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Die Oxyanionen des Chlors finden als Desinfektionsmittel Verwendung, rufen wegen ihrer Anreicherung in der Umwelt aber Bedenken hervor. Ein wasserlösliches Manganporphyrin katalysiert die Dismutation von Chlorit (ClO2−) zu Chlordioxid (ClO2) über eine Abfolge von Elektronen‐ und Atomtransferreaktionen. Eine hochvalente Mangan(IV)‐Oxo‐Spezies wird beobachtet, und das ClO2‐Produkt hemmt die Reaktion (siehe Schema).

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Synthesis and Characterization of the Cationic Porphyrin meso-Tetrakis(2,3,5,6-tetrafluoro-N,N,N-trimethyl-4-aniliniumyl)porphyrin

Cited by 43 publications

References 0 publications

Bioinspired Dismutation of Chlorite to Dioxygen and Chloride Catalyzed by a Water‐Soluble Iron Porphyrin

Bioinspired Dismutation of Chlorite to Dioxygen and Chloride Catalyzed by a Water‐Soluble Iron Porphyrin

Coordination-Induced Spin-State-Switch (CISSS) in water

Chlorite Dismutation to Chlorine Dioxide Catalyzed by a Water‐Soluble Manganese Porphyrin

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