Synthesis and characterization of two new mixed-valent Mn6 complexes derived from a well-explored 2‑hydroxymethyl pyridine along with the use of newly employed carboxylate ions

Reagan, M. A.; Drew, Eric; Zhang, Z. John; Padgett, Clifford W.; Orvis, Jeffery A.; Saha, Arpita

doi:10.1016/j.inoche.2018.09.008

Cited by 2 publications

(2 citation statements)

References 37 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Testing the myriad combinations is necessary to identify the most optimal and advantageous ones, which is a process that is undoubtedly neither easy nor quick. In recent years, a considerable amount of research is dedicated to (among others) the Mn 6 sub-family [ 42 , 226 , 227 ]. This trend is expected to persist, given the adaptability of these species for ligand exchange and property tuning.…”

Section: Discussionmentioning

confidence: 99%

“…Especially, the Mn

species are worth mentioning here. The S

value of Mn

compound derivatives may vary from 4 up to 12 [ 41 , 42 ]. Moreover, these molecules demonstrated remarkable versatility in incorporating diverse organic ligands, rendering them promising and well-suited for surface deposition [ 41 , 43 , 44 ].…”

Section: Characteristics and Main Representatives Of Smmsmentioning

confidence: 99%

See 1 more Smart Citation

Nanostructures as the Substrate for Single-Molecule Magnet Deposition

Adamek,

Pastukh,

Laskowska

et al. 2023

IJMS

View full text Add to dashboard Cite

Anchoringsingle-molecule magnets (SMMs) on the surface of nanostructures is gaining particular interest in the field of molecular magnetism. The accurate organization of SMMs on low-dimensional substrates enables controlled interactions and the possibility of individual molecules’ manipulation, paving the route for a broad range of nanotechnological applications. In this comprehensive review article, the most studied types of SMMs are presented, and the quantum-mechanical origin of their magnetic behavior is described. The nanostructured matrices were grouped and characterized to outline to the reader their relevance for subsequent compounding with SMMs. Particular attention was paid to the fact that this process must be carried out in such a way as to preserve the initial functionality and properties of the molecules. Therefore, the work also includes a discussion of issues concerning both the methods of synthesis of the systems in question as well as advanced measurement techniques of the resulting complexes. A great deal of attention was also focused on the issue of surface–molecule interaction, which can affect the magnetic properties of SMMs, causing molecular crystal field distortion or magnetic anisotropy modification, which affects quantum tunneling or magnetic hysteresis, respectively. In our opinion, the analysis of the literature carried out in this way will greatly help the reader to design SMM-nanostructure systems.

show abstract

Section: Discussionmentioning

confidence: 99%

“…Especially, the Mn

species are worth mentioning here. The S

value of Mn

Section: Characteristics and Main Representatives Of Smmsmentioning

confidence: 99%