Synthesis and Characterizations of ZnS:Cu/ZnS Assisted by 3-Mercaptopropionic Acid

Abstract

3-Mercaptopropionic acid capped core/shell ZnS:Cu(3%)/ZnS doped quantum dots (QDs) where synthesized at 95 °C in basic aqueous solution using the nucleation doping approach methods. The structural and optical properties of the QDs were characterized by X-ray diffraction (XRD) which confirms the cubic phase blende, whereas transmission electron microscopy (TEM) which shows the nanoparticles are spherical. UV-vis spectroscopy and photoluminescence (PL) spectroscopy. The obtained nearly monodisperse QDs have an average diameter of ca. 3.31 nm and a zinc blende crystal structure. The PL emission wavelength was limited between 500 and 510 nm but PL quantum efficiency of ZnS:Cu/ZnS core/shell nanocrystals increased up to 5%. The experimental results demonstrate that this method is effective for the preparation of ZnS:Cu/ZnS quantum dots.

Synthesis of CdS/CdSe Core/Shell Heterostructures Using Ultrasonic Assisted Sol–Gel Method

“…II-VI chalcogenide nano semiconductors are promising materials for scientific and technological applications such as solar cells [1], light emitting diodes [2] and photocatalysts [3] due to their fundamental excitonic properties [4][5][6][7]. Out of them CdS, CdSe and CdTe have shown high extinction coefficient, photo-stability, tunable band gap and good light absorbing capacity make them suitable for effective charge separation in optoelectronic devices [8][9][10][11].…”