Synthesis and crystal structure of 3-ammoniumphenyl sulfone selenate, 3-aminophenyl sulfone [C12H14N2O2S]SeO4 · [C12H12N2O2S]

Physico-chemical study of new supramolecular-architectured hybrid organic–inorganic sulfates incorporating diammoniumdiphenylsulfone cations

“…A series of different organic-inorganic materials (namely 3-ammoniumphenylsulfone selenate, 3-aminophenylsulfone, 3-ammoniumphenylsulfone dihydrogenphosphate phosphoric acid and bis(3-ammoniumphenyl)sulfone dinitrate) were rstly obtained with Mahroug et al in the period of 2011-2013. [29][30][31] By 2017, Kessentini et al had also conrmed the formation of an organic-inorganic 3,3 0 -(DDS)SnCl 6 hybrid system stabilized by different types of hydrogen bonding that are distinguished by their interesting electric properties. 32 Hence, we report here the synthesis, detailed crystallographic analysis, vibrational study, description of the thermal behavior and the optical properties of two new hybrid organicinorganic salts, namely 4,4 0 -diammoniumdiphenylsulfone sulfate (4,4 0 -DDS-S) and 3,3 0 -diammoniumdiphenylsulfone sulfate (3,3 0 -DDS-S).…”

“…4,4 0 -DDS-S 5.218(2)/5.229(2) 120.73(12)/122.24(13) 107.84(17)/107.16(17) 3,3 0 -DDS-S 4.595(2)/4.841(2) 91.18(14)/98.64(14) 100.28(18)/103.22(19) 4,4 0 -Sulfonyldianilinium dinitrate40 4.890(2) 100.86(7) 103.44(9) 3,3 0 -Sulfonyldianilinium bis(dihydrogen phosphate) phosphoric acid solvate29 5.052(2) 108.92(6) 105.02(7) …”