Synthesis and crystal structure of 4-(2-ammonioethyl)morpholin-4-ium dichloridodiiodidocadmate/chloridotriiodidocadmate (0.90/0.10)

Rhouma, Najla Mahbouli; Rayes, Ali; Mezzadri, Francesco; Calestani, G.; Loukil, M.

doi:10.1107/s2056989016013967

Acta Cryst E

2016

DOI: 10.1107/s2056989016013967

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Synthesis and crystal structure of 4-(2-ammonioethyl)morpholin-4-ium dichloridodiiodidocadmate/chloridotriiodidocadmate (0.90/0.10)

Najla Mahbouli Rhouma¹,

Ali Rayes²,

Francesco Mezzadri³

et al.

Abstract: The crystal structure of a new inorganic–organic hybrid material, (C6H16N2O)[CdCl1.90I2.10], consists of 4-(2-ammonioethyl)morpholin-4-ium cations and dichloridodiiodidocadmate/chloridotriiodidocadmate (0.90/0.10) anions connected by hydrogen bonds into a three-dimensional network.

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2023

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Crystal structure of 2-(morpholino)ethylammonium picrate monohydrate

Chidambaranathan¹,

Sivaraj²,

Selvakumar³

2023

Acta Cryst E

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The title compound, C6H15N2O+·C6H2N3O7 −·H2O, was synthesized via slow evaporation of an aqueous solution of picric acid with the substituted morpholine base and crystallized with one cation (C6H15N2O)+, one anion (C6H2N3O7)− and a water molecule in the asymmetric unit. The morpholine ring in the cation adopts a chair conformation. The structure is stabilized by C—H...O, O—H...O, O—H...N and N—H...O hydrogen-bonding interactions and π–π stacking. The intermolecular interactions of the synthesized compound were quantified by Hirshfeld surface analysis.

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Crystal structure of 2-(morpholino)ethylammonium picrate monohydrate

Chidambaranathan¹,

Sivaraj²,

Selvakumar³

2023

Acta Cryst E

View full text Add to dashboard Cite

show abstract

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Synthesis and crystal structure of 4-(2-ammonioethyl)morpholin-4-ium dichloridodiiodidocadmate/chloridotriiodidocadmate (0.90/0.10)

Abstract: The crystal structure of a new inorganic–organic hybrid material, (C6H16N2O)[CdCl1.90I2.10], consists of 4-(2-ammonioethyl)morpholin-4-ium cations and dichloridodiiodidocadmate/chloridotriiodidocadmate (0.90/0.10) anions connected by hydrogen bonds into a three-dimensional network.

Cited by 1 publication

References 12 publications

Crystal structure of 2-(morpholino)ethylammonium picrate monohydrate

Crystal structure of 2-(morpholino)ethylammonium picrate monohydrate

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