Synthesis and Crystal Structure of {[HNEt₃]_2n[Ag₈Ag_4/2(SC₆H₄tBu‐4)₁₂]_n·nC₂H₅OH} and Its Reaction Product with CS₂

Abstract

By using an arylthiolate ligand with a substituent in the paraposition, 4-tBuC 6

Bromide‐Induced Formation of a Highly Symmetric Silver Thiolate Cluster Containing 36 Silver Atoms from an Infinite Polymeric Silver Thiolate

“…[17] This polymer is insoluble in acetonitrile. Upon addition of an aqueous solution of (C 4 H 9 ) 4 N + Br -, the acetonitrile dispersion of the polymer microcrystals quickly became a clear solution.…”

“…[17] 1: In a glass vial, the polymeric silver thiolate (60 mg) was dispersed in acetonitrile (3 mL). A solution containing (C 4 H 9 ) 4 NBr (10 mg) in water (0.1 mL) was then added into the polymer dispersion.…”

“…In the other approach, polymeric silver thiolates were applied as the precursors to react with a reactive sulfide precursor, S(SiMe 3 ) 2 , to yield silver thiolate clusters, which has become very effective in the synthesis of some extra-large silver thiolate nanoclusters. [10,16,17] The possibility of using polymeric silver thiolates to prepare discrete nanoclusters arises mainly because of the strong affinity of sulfide to silver, which facilitates the break down of the polymeric chain. Similarly to sulfide, a halide anion (e.g.…”

A luminescent [Ag3S3]n-tube based metal–organic framework

“…Over the past several decades, the silver(I) complexes with sulfur-containing ligands have attracted much attention because they not only show structural diversity [1][2][3], but also have a wide range of application in medicine, in analytical chemistry or in the polymer industry [4,5] and even in semiconductor materials [6,7]. In the field, the majority of researches have mainly been devoted to polynuclear silver(I) clusters [8][9][10][11] but polymeric complexes, especially those with high-dimensional networks, are less investigated [12][13][14]. The heterocyclic thione ligands, which are characterized by thione-thiol tautomerism, represent one type of the most versatile sulfur donor ligands.…”

“…In the field, the majority of researches have mainly been devoted to polynuclear silver(I) clusters [8-11] but polymeric complexes, especially those with high-dimensional networks, are less investigated [12][13][14]. The heterocyclic thione ligands, which are characterized by thione-thiol tautomerism, represent one type of the most versatile sulfur donor ligands.…”