Synthesis and Crystal Structures of Cs5Nb2S4X9 - Double Salts Containing New Cluster Anions [Nb2(μ-S2)2X8]4- (X = Cl, Br)

Sokolov, Maxim N.; Imoto, Hideo; Saito, Taro; Fedorov, V. E.

doi:10.1002/(sici)1521-3749(199906)625:6<989::aid-zaac989>3.0.co;2-g

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Cited by 14 publications

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ChemInform Abstract: Synthesis and Crystal Structures of Cs₅Nb₂S₄X₉ — Double Salts Containing New Cluster Anions [Nb₂(μ‐S₂)₂X₈]^4‐ (X: Cl, Br).

Sokolov¹,

Imoto²,

Saito³

et al. 1999

ChemInform

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Synthesis and Crystal Structures of Cs 5 Nb 2 S 4 X 9 -Double Salts Containing New Cluster Anions [Nb 2 (µ-S 2 ) 2 X 8 ] 4− (X: Cl, Br).-The isotypic compounds (IV) crystallize in the tetragonal space group Immm with Z = 2. The compounds contain the new [Nb 2 S 4 X 8 ] 4− anion with the Nb atoms in a distorted square antiprismatic coordination with four S and four X atoms. These anions can be viewed as excised building blocks of polymeric Nb 2 S 2 X 2 solids. The extra halogen atom resides in the center of an octahedron formed by six Cs + or H 3 O + ions. -(SOKOLOV, MAXIM

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ChemInform Abstract: Synthesis and Crystal Structures of Cs₅Nb₂S₄X₉ — Double Salts Containing New Cluster Anions [Nb₂(μ‐S₂)₂X₈]^4‐ (X: Cl, Br).

Sokolov¹,

Imoto²,

Saito³

et al. 1999

ChemInform

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Octahedral Niobium Thiocyanato Complexes Containing [Nb6Cl9O3] Cluster Core: Syntheses, Crystal Structures and Evidences of NCS Ligand Exchange

Naumov¹,

Cordier²,

Ovoschnikov³

et al. 2008

J Clust Sci

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Crystal structure of Tl5{[Nb2S4Br8]Br}

et al. 2008

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Synthesis and Crystal Structures of Cs5Nb2S4X9 - Double Salts Containing New Cluster Anions [Nb2(μ-S2)2X8]4- (X = Cl, Br)

Cited by 14 publications

References 8 publications

ChemInform Abstract: Synthesis and Crystal Structures of Cs₅Nb₂S₄X₉ — Double Salts Containing New Cluster Anions [Nb₂(μ‐S₂)₂X₈]^4‐ (X: Cl, Br).

ChemInform Abstract: Synthesis and Crystal Structures of Cs₅Nb₂S₄X₉ — Double Salts Containing New Cluster Anions [Nb₂(μ‐S₂)₂X₈]^4‐ (X: Cl, Br).

Octahedral Niobium Thiocyanato Complexes Containing [Nb6Cl9O3] Cluster Core: Syntheses, Crystal Structures and Evidences of NCS Ligand Exchange

Crystal structure of Tl5{[Nb2S4Br8]Br}

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Synthesis and Crystal Structures of Cs5Nb2S4X9 - Double Salts Containing New Cluster Anions [Nb2(μ-S2)2X8]4- (X = Cl, Br)

Cited by 14 publications

References 8 publications

ChemInform Abstract: Synthesis and Crystal Structures of Cs5Nb2S4X9 — Double Salts Containing New Cluster Anions [Nb2(μ‐S2)2X8]4‐ (X: Cl, Br).

ChemInform Abstract: Synthesis and Crystal Structures of Cs5Nb2S4X9 — Double Salts Containing New Cluster Anions [Nb2(μ‐S2)2X8]4‐ (X: Cl, Br).

Octahedral Niobium Thiocyanato Complexes Containing [Nb6Cl9O3] Cluster Core: Syntheses, Crystal Structures and Evidences of NCS Ligand Exchange

Crystal structure of Tl5{[Nb2S4Br8]Br}

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ChemInform Abstract: Synthesis and Crystal Structures of Cs₅Nb₂S₄X₉ — Double Salts Containing New Cluster Anions [Nb₂(μ‐S₂)₂X₈]^4‐ (X: Cl, Br).

ChemInform Abstract: Synthesis and Crystal Structures of Cs₅Nb₂S₄X₉ — Double Salts Containing New Cluster Anions [Nb₂(μ‐S₂)₂X₈]^4‐ (X: Cl, Br).