Synthesis and crystallographic characterization of thiazole-2-dithiocarboxylate methyl ester complexes of chromium, tungsten and iron carbonyls †

Smartphone-based digitized recognition of As3+ along with its effectual mitigation in water using a benzothiazole-functionalized molecular scaffold

“…In the thiazole part, the endo-cyclic -CQN, C-S bond distance and oCNC bond angle were found to be 1.29 Å, 1.75 Å and 109.51 respectively, which are almost similar to the conventional benzothiazole moiety with regard to endo-cyclic -CQN (1.31 Å), C-S (1.733 Å) bond length and oCNC (110.621) bond angle. 12 Moreover, exo-cylic -C-N, -N-N, -CQN and C-C bond distances were found to be 1.362 Å, 1.345 Å, 1.29 Å and 1.466 Å respectively. In the acrydine part, the endo-cyclic -CQN bond distance and the oCNC bond angle were found to be 1.35 Å and 1181 respectively.…”

Mono- and bi-dentate Group 6-coordinated and titanium-containing isocyanide ligands prepared from benzoxazole

“…We have previously also observed disubstitution despite the presence of only one labile ligand in Group 6 metal complexes, with ligands containing exocyclic S-and endocyclic N-and S-donor atoms. 8 It is significant that the lithiated oxazole prefers C-isocyanide coordination to M(CO) 5 (M = Cr, Mo, W) whereas CN-C 6 H 4 -OH-o readily and quantitatively converts into the aminocarbene complexes [(CO) 5 MCNHC 6 H 4 O-o]. 9 The oxophilic titanium complex, however, would drive the equilibrium completely away from a carbene form towards the isocyanide containing isomer.…”