2006
DOI: 10.1002/chin.200651214
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Synthesis and Electrical Transport of Single‐Crystal NH4V3O8 Nanobelts.

Abstract: Nanotechnology V 1505Synthesis and Electrical Transport of Single-Crystal NH 4 V 3 O 8 Nanobelts. -Monoclinic single-crystalline nanobelts of the title compound with widths of 80-180 nm, thicknesses of 50-100 nm, and lengths up to tens of micrometers are synthesized at large scale from an aqueous solution of NH4VO3 containing HCl (autoclave, pH 1.5, 180°C, 36 h). The samples are characterized by XRD, FTIR spectroscopy, SEM, and TEM. The nanobelts exhibit nonlinear, symmetric current/voltage characteristics, wi… Show more

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Cited by 6 publications
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“…The logarithm of the current density [ln( J )] was also plotted against the square root of the electric field [ E 1/2 ] in Figure . It can be determined that the straight-line nature observed at a medium electric field between 240 and 360 V/cm implied the Schottky mechanism, , as shown in Figure a, while at high electrical fields, the observed straight line in Figure b was related to the Poole-Frenkel mechanism. , It is anticipated that the novel silver trimolybdate single-crystalline NWs may have unique applications in microelectrodes or microsensors, which is similar to the novel vanadate materials. …”
Section: Resultsmentioning
confidence: 91%
“…The logarithm of the current density [ln( J )] was also plotted against the square root of the electric field [ E 1/2 ] in Figure . It can be determined that the straight-line nature observed at a medium electric field between 240 and 360 V/cm implied the Schottky mechanism, , as shown in Figure a, while at high electrical fields, the observed straight line in Figure b was related to the Poole-Frenkel mechanism. , It is anticipated that the novel silver trimolybdate single-crystalline NWs may have unique applications in microelectrodes or microsensors, which is similar to the novel vanadate materials. …”
Section: Resultsmentioning
confidence: 91%
“…The dimensions of these hexagons network of hydrogen bonds [17]. The characteristic band for crystal water around 1620 cm -1 [15] is absent, which provides evidence for the pristine material being water-free NH 4 V 3 O 8 . This could not be achieved by using the conventional hydrothermal route [17].…”
Section: Resultsmentioning
confidence: 96%
“…The traditional method is to use raw NH 4 VO 3 as vanadium source, and a mineral acid (HCl or H 2 SO 4 ) to adjust the initial pH value and to accomplish an -4 -acid hydrolysis [15,16]. Hydrothermal synthesis is a more efficient method to produce NH 4 V 3 O 8 [17].…”
Section: Introductionmentioning
confidence: 99%
“…One-dimensional (1D) inorganic nanomaterials with various shapes and morphologies, such as nanotubes, nanowires, nanorods and nanobelts generally show enhanced physiochemical applications in various areas due to their high surface to size effects and reduced dimensionality not only have been attracting a great deal of research interest in recent years, but also they have been emerging as one of the most powerful and diverse classes of functional nanomaterials that are having a key impact on science and technology (Huang et al, 2001;Song et al, 2005;Comini et al, 2005;Mai et al, 2006;Fang et al, 2011a,b;Li et al, 2012;Peng et al, 2014). In particular, as one of the most important 1D-material structures quasione-dimensional nanobelts appear to have unique ability to combine a number of essential diagnostic, imaging, delivery and dosage properties and thus can be functionalized accordingly (Pan et al, 2001;Mo et al, 2002;Wang, 2004;Yu et al, 2008;Ahmad et al, 2011).…”
Section: Introductionmentioning
confidence: 99%