Synthesis and electrochemical properties for LiNiO2 substituted by other elements

Kubo, K.; Fujiwara, Masashi; Yamada, Shǔji; Arai, Shinji; Kanda, M.

doi:10.1016/s0378-7753(97)02530-5

Cited by 66 publications

(31 citation statements)

References 5 publications

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“…There were peaks of fluorine substitution in the diffraction pattern, which is consistent with previous reports [12,20,21,22,23]. In addition, it was reported that the small ionic radius of fluorine leads to a change in the lattice constant.…”

Section: Resultssupporting

confidence: 91%

Electrochemical Performances of the Fluorine-Substituted on the 0.3Li₂MnO₃·0.7LiMn_0.60Ni_0.25Co_0.15O₂Cathode Material

Kim¹,

Jin²,

Park³

et al. 2014

Journal of Electrochemical Science and Technology

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Section: Resultssupporting

confidence: 91%

Electrochemical Performances of the Fluorine-Substituted on the 0.3Li₂MnO₃·0.7LiMn_0.60Ni_0.25Co_0.15O₂Cathode Material

Kim¹,

Jin²,

Park³

et al. 2014

Journal of Electrochemical Science and Technology

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“…It is also considered that the increase of lithium content in Li x NiO 2 decreases the oxidation state of some Ni ions from Ni 3C to Ni 2C , which might increase the formation of an electrochemically inert phase in the LiNiO 2 since Ni 2C has a more stable state [68]. This may impede the motion of the lithium ions leading to the deterioration of the electrode during charge and discharge.…”

Section: Electrochemistry Of Liniomentioning

confidence: 99%

Various aspects of LiNiO₂chemistry: A review

Kalyani

Kalaiselvi²

2005

Science and Technology of Advanced Materials

301

170

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Despite the appearance of ever first report on the synthesis of LiNiO 2 in 1954, active research to identify and evaluate its suitability as an electrode material in rechargeable lithium batteries started only in late 80's. Following this, numerous articles discussed the synthesis, electrochemical behavior and the problems associated with the compound. In this connection, the present communication reviews certain important experimental results obtained by different research groups on various aspects of LiNiO 2 , in order to understand the significance of LiNiO 2 as a potential cathode material for rechargeable lithium batteries. Also selected type of methodologies adopted to synthesize the title compound have also been discussed to substantiate the dependence of electrochemical behavior of LiNiO 2 on the method of synthesis and reaction conditions. The subject has been discussed at length and may provide useful information on the properties of LiNiO 2 and may enable the fabrication of tailor made nickel-based electrode materials for 'next generation' lithium or lithium-ion batteries along with the highlights of doped and coated derivatives of LiNiO 2 .

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“…During the past 15 years, lithium transition metal oxides such as LiCoO 2 [1][2][3], LiMn 2 O 4 [4][5][6] and LiNiO 2 [7][8][9] have been investigated intensively for use as cathode materials in lithium-ion batteries.…”

Section: Introductionmentioning

confidence: 99%

Synthesis of LiNi1/3Co1/3Mn1/3O2 cathode materials by using a supercritical water method in a batch reactor

Lee

Viet

et al. 2010

Electrochimica Acta

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Synthesis and electrochemical properties for LiNiO2 substituted by other elements

Cited by 66 publications

References 5 publications

Electrochemical Performances of the Fluorine-Substituted on the 0.3Li₂MnO₃·0.7LiMn_0.60Ni_0.25Co_0.15O₂Cathode Material

Electrochemical Performances of the Fluorine-Substituted on the 0.3Li₂MnO₃·0.7LiMn_0.60Ni_0.25Co_0.15O₂Cathode Material

Various aspects of LiNiO₂chemistry: A review

Synthesis of LiNi1/3Co1/3Mn1/3O2 cathode materials by using a supercritical water method in a batch reactor

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Synthesis and electrochemical properties for LiNiO2 substituted by other elements

Cited by 66 publications

References 5 publications

Electrochemical Performances of the Fluorine-Substituted on the 0.3Li2MnO3·0.7LiMn0.60Ni0.25Co0.15O2Cathode Material

Electrochemical Performances of the Fluorine-Substituted on the 0.3Li2MnO3·0.7LiMn0.60Ni0.25Co0.15O2Cathode Material

Various aspects of LiNiO2chemistry: A review

Synthesis of LiNi1/3Co1/3Mn1/3O2 cathode materials by using a supercritical water method in a batch reactor

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Product

Resources

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Electrochemical Performances of the Fluorine-Substituted on the 0.3Li₂MnO₃·0.7LiMn_0.60Ni_0.25Co_0.15O₂Cathode Material

Electrochemical Performances of the Fluorine-Substituted on the 0.3Li₂MnO₃·0.7LiMn_0.60Ni_0.25Co_0.15O₂Cathode Material

Various aspects of LiNiO₂chemistry: A review