Synthesis and electrochemical properties of Pb3 − x M x Nb2O8 (M = Sr, Ba) solid solutions

Podkorytov, A. L.; Shtin, S. A.; Khusaenova, A. R.; Kudakaeva, S. R.; Goncharevich, A. V.

doi:10.1134/s0020168512090129

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2013

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“…In addition to conventional applications of ceramic materials, a new area in the use of ceramics as elec trode active membrane materials for ion selective electrodes has recently been the subject of consider able attention [2][3][4][5][6][7]. The possibility of doping host compounds with heavy metal ions allows one to obtain modified materials capable of ↔ exchange, resulting in a potential jump across the interface [6,7].…”

Section: Introductionmentioning

confidence: 99%

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Ga- and Ti-containing Ni4Nb2O9-based solid solutions for Ni-Selective electrodes

et al. 2013

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Gallium and titanium containing niobates with the compositions Ni 4 -x Ga 2/3x Nb 2 O 9 and Ni 4 -x Ti x/2 Nb 2 O 9 have been synthesized and their physicochemical properties have been studied. Their unit cell parameters have been determined by X ray diffraction and their electrical conductivity has been mea sured as a function of temperature. According to thermomechanical analysis data, the niobates undergo no phase transitions. Some of the solid solutions have been used to fabricate Ni selective electrodes, which have been tested in ion selective measurements. In a number of cases, satisfactory results have been obtained.

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Section: Introductionmentioning

confidence: 99%

“…The possibility of doping host compounds with heavy metal ions allows one to obtain modified materials capable of ↔ exchange, resulting in a potential jump across the interface [6,7].…”

Section: Introductionmentioning

confidence: 99%