Synthesis and end-group control of soluble, high-molecular-weight hyperbranched poly(phenylene thienylene)s by non-stoichiometric A2 + B3 Suzuki-Miyaura polycondensation without gelation
Suzuki-Miyaura polycondensation of tri- or tetra(bromoarylsilane) 1 with arylenediboronic acid (ester) 4 in the presence of tBu3PPd precatalyst 3 was investigated for the synthesis of silicon-containing hyperbranched aromatic polymers by...
Suzuki-Miyaura polycondensation of tri- or tetra(bromoarylsilane) 1 with arylenediboronic acid (ester) 4 in the presence of tBu3PPd precatalyst 3 was investigated for the synthesis of silicon-containing hyperbranched aromatic polymers by...
According to the theory established by Carothers and Flory, stoichiometric control of monomers is necessary for efficient step-growth polymerization of AA-type and BB-type monomers in a single-phase solution. This review...
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