The
application of superabsorbent polymers (SAPs) is hindered because
their absorption capability is greatly affected by the electrolytes
in a solution. A novel modified water-absorbent polymer was fabricated
by solution polymerization of sulfamic acid-modified starch and acrylic
acid; the swelling ratios of this absorbent polymer were 1026 g/g
in deionized water and 145 g/g in 0.9% sodium chloride solution and
increased by 99.5 and 13.4%, respectively, when compared with ordinary
starch-grafted acrylic SAPs. The water absorption capacity was measured
in water at different pH values, salt concentrations, and temperatures.
In addition, water and fertilizer retentions were studied by simulated
leaching tests in a soil column. The results showed that water absorption
capacities of the modified SAP in salt solutions were improved due
to the adsorption and transfer of water molecules by the sulfonic
acid groups. Compared to the losses when there was no superabsorbent
treatment, the water, nitrate, ammonium nitrogen, and water-soluble
potassium losses during the salt-tolerant superabsorbent treatment
were significantly reduced by 18.5, 22.8, 88.0, and 63.8%, respectively.
The method introduced in this study could guide the development and
wide application of salt-tolerant SAPs in agriculture and horticulture.