2003
DOI: 10.1002/chin.200311178
|View full text |Cite
|
Sign up to set email alerts
|

Synthesis and Fragmentation of New 2‐Phosphabicyclo[2.2.2]octene 2‐Oxides.

Abstract: Organo-phosphorus compoundsOrgano-phosphorus compounds S 0080 Synthesis and Fragmentation of New 2-Phosphabicyclo[2.2.2]octene 2-Oxides. -(KEGLEVICH*, G.; SZELKE, H.; TAMAS, A.; HARMAT, V.; LUDANYI, K.; VASKO, A. G.; TOKE, L.; Heteroat. Chem. 13 (2002) 7, 626-632; Dep. Org. Chem. Technol., Tech. Univ. Budapest, H-1521 Budapest, Hung.; Eng.) -M. Kowall 11-178

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...
1
1
1

Citation Types

0
3
0

Year Published

2003
2003
2014
2014

Publication Types

Select...
2

Relationship

0
2

Authors

Journals

citations
Cited by 2 publications
(3 citation statements)
references
References 1 publication
0
3
0
Order By: Relevance
“…The reaction involves a condensation reaction between the two molecules of the substrate and also incorporating a tetracyanoethylene moiety. It may be recalled that the Diels-Alder reaction of two isomeric units of the dihydrophosphinine oxide led to phosphabicyclooctenes [5]. The mechanism of the novel reaction discussed is yet to be studied further.…”
Section: Figure 2 Continuedmentioning
confidence: 97%
See 1 more Smart Citation
“…The reaction involves a condensation reaction between the two molecules of the substrate and also incorporating a tetracyanoethylene moiety. It may be recalled that the Diels-Alder reaction of two isomeric units of the dihydrophosphinine oxide led to phosphabicyclooctenes [5]. The mechanism of the novel reaction discussed is yet to be studied further.…”
Section: Figure 2 Continuedmentioning
confidence: 97%
“…The "traditional" phosphabicyclooctenes are obtained by the Diels-Alder reaction of 1,2-dihydrophosphinine oxides with maleic acid derivatives [1,2]. Recently, we have aimed at the synthesis of new types of precursors, such as diaza derivatives [4,5] or the dimers of dihydrophosphinine oxides [5,6]. In this paper, we describe the reactions of dihydrophosphinine oxides with tetracyanoethylene, which is a versatile dienophile that sometimes gives quite unexpected results [7][8][9].…”
Section: Introductionmentioning
confidence: 97%
“…According to another protocol, phosphabicyclo[2.2.2]octadieneor -octene derivatives served as the precursors of methylenephosphine oxides giving the phosphinates by phosphorylation of the alcohols or phenols. The fragmentation was achieved photo chemically or thermally (Scheme 16) [85][86][87][88][89][90][91][92].…”
Section: Scheme 15mentioning
confidence: 99%