Synthesis and fungicidal activity of S-amino derivatives of O-alkyldithiocarbonic acids

Bakbardina, O. V.; Pukhnyarskaya, I. Yu.; Газалиева, М. А.; Фазылов, С. Д.; Makarov, E. M.

doi:10.1134/s1070427206100375

Cited by 10 publications

(2 citation statements)

References 2 publications

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“…Subsequently, extensive structural analyses were performed by Haiduc and Tiekink, which showed that these ligands can coordinate to metal atoms in a monodentate, isobidentate, or anisobidentate fashion. Metal xanthates are extensively used as pharmaceuticals [15], fungicides [16], pesticides [17], corrosion inhibitors [18], agricultural reagents [19], and quite recently in therapy for HIV infections [20]. The last two decades have witnessed a tremendous development of new radical reactions designed for organic synthesis [21,22].…”

Section: Introductionmentioning

confidence: 99%

O-Tolyl/benzyl dithiocarbonates of phosphorus(III) and (V): syntheses and characterization

et al. 2012

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O-Tolyl/benzyl dithiocarbonates, ROCS 2 Na (R = o-, m-, or p-CH 3 C 6 H 4 -, and -CH 2 C 6 H 5 ), were synthesized and characterized. These new ligands reacted with PCl 3 /POCl 3 in refluxing toluene which resulted in the formation of phosphorus(III) and phosphorus(V) tolyl/ benzyl dithiocarbonates corresponding to [(ROCS 2 ) n PCl 3-n ] and [(ROCS 2 ) n POCl 3-n ] (R = o-, m-, or p-CH 3 C 6 H 4 -, and -CH 2 C 6 H 5 ; n = 1, 2, 3). These pale yellow liquid compounds were characterized by IR, mass, and NMR ( 1 H, 13 C, and 31 P) spectral studies, which suggest the dithiocarbonate ligands bind in a monodentate mode leading to P-S-C linkages in these derivatives.

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Section: Introductionmentioning

confidence: 99%

O-Tolyl/benzyl dithiocarbonates of phosphorus(III) and (V): syntheses and characterization

et al. 2012

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“…Alkyldithiocarbonates, more commonly referred to as xanthates, were first prepared by Semeniuc et al [ 1 ]. Their applications as vulcanizers [ 2 ], fungicides [ 3 ], and flotation agents [ 4 , 5 ] in metallurgy have been described in the literature. The synthetic and structural chemistry of xanthates witnessed increased attention through the pioneering work of Winter [ 6 ], Tiekink and Winter [ 7 ], Hoskins and Pannan [ 8 ], and Dakternieks et al [ 9 ].…”

Section: Introductionmentioning

confidence: 99%

Syntheses, Characterization, Thermal, and Antimicrobial Studies of Lanthanum(III) Tolyl/Benzyldithiocarbonates

Andotra

Kalgotra

Pandey

2014

Bioinorganic Chemistry and Applications

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Lanthanum(III) tris(O-tolyl/benzyldithiocarbonates), [La(ROCS2)] (R = o-, m-, p-CH3C6H4 and C6H5CH2), were isolated as yellow solid by the reaction of LaCl3 ·7H2O with sodium salt of tolyl/benzyldithiocarbonates, ROCS2Na (R = o-, m-, p-CH3C6H4 and C6H5CH2), in methanol under anhydrous conditions in 1 : 3 molar ratio. These complexes have formed adducts with nitrogen and phosphorus donor molecules by straightforward reaction of these complexes with donor ligands, which have the composition of the type [La(ROCS2)3 ·nL] (where n = 2, L = NC5H5 or P(C6H5)3 and n = 1, L = N2C12H8 or N2C10H8). Elemental analyses, mass, IR, TGA, and heteronuclear NMR (1H, 13C and 31P) spectroscopic studies indicated bidentate mode of bonding by dithiocarbonate ligands leading to hexacoordinated and octacoordinated geometry around the lanthanum atom. Antimicrobial (antifungal and antibacterial) activity of the free ligands and some of the complexes have also been investigated which exhibited significantly more activity for the complexes than the free ligands.

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Synthetic, spectroscopic, thermal, and structural studies of antimony(III) bis(pyrrolidinedithiocarbamato)alkyldithiocarbonates

Chauhan

Bakshi

2010

J Therm Anal Calorim

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Synthesis and fungicidal activity of S-amino derivatives of O-alkyldithiocarbonic acids

Cited by 10 publications

References 2 publications

O-Tolyl/benzyl dithiocarbonates of phosphorus(III) and (V): syntheses and characterization

O-Tolyl/benzyl dithiocarbonates of phosphorus(III) and (V): syntheses and characterization

Syntheses, Characterization, Thermal, and Antimicrobial Studies of Lanthanum(III) Tolyl/Benzyldithiocarbonates

Synthetic, spectroscopic, thermal, and structural studies of antimony(III) bis(pyrrolidinedithiocarbamato)alkyldithiocarbonates

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