Synthesis and incorporation of poly(methyl methacrylate) microspheres with UV stabilizers in wood clear coating binder

One of the major issues in the wood industry is the durability of clear coatings. The addition of organic ultraviolet absorbers (UVAs) improves coating resistance by the absorption and conversion of UV radiation into harmless heat. Organic UVAs are, however, easily degraded by free radicals produced by photodegradation inside the polymer matrix and are prone to migration in the coating. In this study, commercial UVAs and hindered amine light stabilizers (HALS) entrapped into poly(methyl methacrylate) (PMMA) microspheres and CaCO3 templates coated with UV-responsive polymers were added into clear acrylic water-based coating formulation. Artificial accelerated weathering experiments were performed on each formulation. Raman spectroscopy mapping was performed to visualize the concentration and distribution of UVAs and HALS. This study also presents a comparison of the mechanical properties of coatings obtained by dynamic mechanical analysis. Results showed that coating mechanical properties were improved when using encapsulated UVAs and HALS inside PMMA microspheres. The color change of the wood and coating system was minimized and the production of photo-oxidation compounds in the binder was also limited.

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Introducing a Novel Application of Bio-Based Fillers Based on Rice Bran Wax Infused with Green Tea: Transitioning from a Cosmetic Additive to a Multifunctional Pigment for Wood Paints

Calovi,

Rossi

2024

Applied Sciences

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This study aims to assess the functionality of a bio-derived additive, comprising rice bran wax infused with green tea, as an environmentally sustainable and adaptable pigment for wood coatings. Additionally, the effectiveness of the bio-based additive, in conjunction with a specialized UV absorber to enhance color consistency under harsh conditions, was examined. Aesthetic impact was analyzed through evaluations of color, gloss, and surface roughness. Moreover, the stability of the wax-based powder in aggressive environments was characterized by subjecting samples to UV-B and climatic chamber exposure. The barrier properties of the additive were investigated using a water uptake test and contact angle measurements, while liquid resistance tests were conducted to gauge its efficacy. Lastly, the protective role of the bio-based additive was analyzed through scrub tests and surface analysis using scanning electron microscopy. Findings underscored the versatility of the green additive as a multifunctional pigment, offering not only color enhancement but also robust protective capabilities. Its unique combination of color, mattifying effect, barrier enhancement, and protective function position it as an attractive bio-based additive for wood coatings with functional applications.

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Synthesis and incorporation of poly(methyl methacrylate) microspheres with UV stabilizers in wood clear coating binder

Cited by 3 publications

References 25 publications

Enhancing wood coatings with red beetroot-derived pigments: Investigating synergy with UV absorber and composite filler for improved durability and aesthetics

Enhancing wood coatings with red beetroot-derived pigments: Investigating synergy with UV absorber and composite filler for improved durability and aesthetics

Comparison of two encapsulation systems of UV stabilizers on the UV protection efficiency of wood clear coats

Introducing a Novel Application of Bio-Based Fillers Based on Rice Bran Wax Infused with Green Tea: Transitioning from a Cosmetic Additive to a Multifunctional Pigment for Wood Paints

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