Synthesis and modification of amine-terminated maleic anhydride‑butyl acrylate copolymer and investigation of adsorption properties for cadmium (II) ions (Cd2+)

Yılmaz, Ersen; Erenler, Fatih Mehmet; Boztuğ, Ali

doi:10.1016/j.molstruc.2020.128924

Cited by 6 publications

(4 citation statements)

References 32 publications

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“…By this way, it will be transformed into a more flexible and easier to process material 6,7 . Polymers that are miscible with PVC can also be used for plasticizing and improving thermal properties; however, there are a few polymers that can be mixed with PVC without using a compatibilizer 8–11 …”

Section: Introductionmentioning

confidence: 99%

“…6,7 Polymers that are miscible with PVC can also be used for plasticizing and improving thermal properties; however, there are a few polymers that can be mixed with PVC without using a compatibilizer. [8][9][10][11] PMMA is a transparent thermoplastic, whose trade name is acrylic, plexiglass, and perspex. Tensile strength, bending strength, transparency, polishability, and UV tolerance; It is an economical alternative to polycarbonate (PC) in situations where impact resistance is more important than chemical resistance and heat resistance.…”

Section: Introductionmentioning

confidence: 99%

“…In another study, Imren D. et al made PVC and EVA miscible with a maleic anhydride‐based compatibilizer and improved its thermomechanical properties 1 . Materials similar to the chosen Maleic anhydride based agent as a compatibilizer were used in our previous studies and successful results were obtained on different polymer pairs 1–3,11 . The advantage of this study from previous studies is that the compatibilizer used was synthesized in our own laboratory and the mixtures were prepared by solution casting, which is a simple and inexpensive process.…”

Section: Introductionmentioning

confidence: 99%

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Compatibilization of polyvinyl chloride ‐ polymethyl methacrylate polymer blends with maleic anhydride‐styrene‐methyl methacrylate terpolymer

Yılmaz

2021

J of Applied Polymer Sci

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In this study, nonmiscible polyvinyl chloride (PVC) and polymethyl methacrylate (PMMA) polymers were made miscible by using MA‐St‐MMA terpolymer as a compatibilizer. Maleic anhydride‐styrene‐methyl methacrylate (MA‐St‐MMA) terpolymer was synthesized in our laboratory and used. The synthesized terpolymer was determined by FT‐IR spectroscopy. Equal mass PVC/PMMA mixture samples were prepared in series and the compatibilizer terpolymer varying between 2% and 10% by mass was added to the samples and the effect of the added terpolymer on the miscibility was determined viscometrically, thermally, mechanically and, visually. With the addition of the compatibilizer, the two components in the mixture behave like a single polymer with a single glass transition temperature (Tg) and the mixture became compatible. As a result of viscometric experiments, it has been determined that with the added MA‐St‐MMA terpolymer, the Δb value derivated from the Krigbaum‐Wall equation which is the miscibility parameter of a mixture shifted into the positive (+) zone indicating that the two polymers became miscible. By visual analysis, it was observed that the added terpolymer reduced the opaque appearance and the phase separations of the mixture. From the tensile test, a significant improvement in impact toughness was observed. When all the data obtained were evaluated, it was determined that the synthesized MA‐St‐MMA terpolymer was a suitable compatibilizer for the mixture of PVC and PMMA.

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Section: Introductionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

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Compatibilization of polyvinyl chloride ‐ polymethyl methacrylate polymer blends with maleic anhydride‐styrene‐methyl methacrylate terpolymer

Yılmaz

2021

J of Applied Polymer Sci

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“…Many researchers have investigated the possibility of eliminating cadmium ions from an aqueous solution (Bagheri et al, 2019;Es-sahbany et al, 2021). One of the most applied methods to remove cadmium ions is the adsorption process (Sun et al, 2019;Yang et al, 2018;Yilmaz et al, 2020;Zhang et al, 2021). For example, hydroxyapatite porous materials were used as adsorbents for cadmium removal (Ramdania et al, 2020).…”

Section: Introductionmentioning

confidence: 99%

Fly Ash Magnetic Adsorbent for Cadmium Ion Removal From an Aqueous Solution

Buema

Lupu

Chiriac

et al. 2021

JALSE

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The fly ash generated from a Romanian power plant was used as a starting material in this study. The aim of the study was to obtain a low cost material based on the treatment of fly ash with Fe3O4 for utilization as an adsorbent for cadmium ion removal. The adsorbent that was synthesized was characterized using different techniques. The adsorption process was investigated by the batch technique at room temperature. The quantity of cadmium ion adsorbed was measured spectrophotometrically. The experimental data showed that the material can remove cadmium ions at all three working concentrations. The adsorption capacity increased with an increase in concentration, respectively contact time. The results were analyzed through two kinetic models: pseudo first order and pseudo second order. The kinetics results of cadmium adsorption onto a magnetic material are in good agreement with a pseudo second order model, with a maximum adsorption capacity of 4.03 mg/g, 6.73 mg/g, and 9.65 mg/g. Additionally, the pseudo second order model was linearized into its four types. The results indicated that the material obtained show the ability to remove cadmium ions from an aqueous solution.

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Treatment of heavy metals containing wastewater using biodegradable adsorbents: A review of mechanism and future trends

Anderson

Anbarasu²,

Pasupuleti

et al. 2022

Chemosphere

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Synthesis and modification of amine-terminated maleic anhydride‑butyl acrylate copolymer and investigation of adsorption properties for cadmium (II) ions (Cd2+)

Cited by 6 publications

References 32 publications

Compatibilization of polyvinyl chloride ‐ polymethyl methacrylate polymer blends with maleic anhydride‐styrene‐methyl methacrylate terpolymer

Compatibilization of polyvinyl chloride ‐ polymethyl methacrylate polymer blends with maleic anhydride‐styrene‐methyl methacrylate terpolymer

Fly Ash Magnetic Adsorbent for Cadmium Ion Removal From an Aqueous Solution

Treatment of heavy metals containing wastewater using biodegradable adsorbents: A review of mechanism and future trends

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