Synthesis and phase transitions of iron phosphate

Research status in preparation of FePO4: a review

“…FePO 4 changes into a trigonal system at 650°C. When the temperature rises to 705°C, an α-β phase transition from a P6222 to a P31121 space group occurs [34]. Compared to the tetragonal system of LiFePO 4 , FeO 6 octahedron is replaced by FeO 4 tetrahedron in the trigonal system [35] (Fig.…”

Low temperature heat capacity Study of Fe(PO3)3 and Fe2P2O7

“…Recently, iron phosphate compounds have attracted considerable research interest in the field of material science due to their outstanding chemical, thermal, electrical and magnetic properties [1][2][3][4][5]. Crystalline and amorphous iron phosphate materials have been developed and applied widely in various technologically important fields such as catalysis [6][7], electrochemistry [8][9][10][11], optical and magnetic materials [12][13][14][15][16], biosensor fabrication [17], bio-absorbable glass fibers [18], industrial coatings [19], and tissue engineering [20]. Moreover, the high chemical durability of iron phosphate glasses makes them suitable as alternative materials for safe immobilization and permanent disposal of a variety of high-level nuclear waste [3,[21][22][23][24][25][26][27].…”

Thermal stability of glasses from the Fe4(P2O7)3–Fe(PO3)3 system

“…Crystalline iron phosphate compounds have been developed for several applications, including catalysts, optical materials and electrodes [1][2][3][4][5]. Chemically durable iron phosphate glasses have been studied as alternative materials for vitrifying high-level nuclear waste [6][7][8][9][10].…”