2024
DOI: 10.1021/acs.inorgchem.4c02741
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Synthesis and Photochemical Properties of Heterometallic Ti–Cu Ring Clusters Constructed from Myo-Inositol Ligand

Li Liu,
Xinyu Zhang,
Yaomei Fu
et al.

Abstract: Incorporating heterometals into titanium–oxygen clusters represents an effective approach to adjusting the band gap and absorption properties. Herein, a family of heterometallic Ti–Cu clusters was synthesized under solvothermal conditions. The unique structural feature of these clusters is the formation of ring clusters with myo-inositol ligands serving as structure-directing ligands. The myo-inositol ligand, as a typical polyol ligand, demonstrates flexible and distinctive coordination modes capable of chelat… Show more

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