2016
DOI: 10.13005/ojc/320413
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Synthesis and Photophysical Properties of Rhenium(I)-Alkynyl Molecular Rectangles

Abstract: A series of highly conjugated, rigid Re(I)-based molecular rectangles {[fac-Re(CO) 3 Br] 2 (µ-bpy) (µ-L)} 2 (1, L = 1,4-bis(42 -pyridylethynyl)benzene, bpeb; 2, L = 1,4-bis(42 -pyridylethynyl)naphthalene, bpen; 3, L = 1,4-bis(42 -pyridylethynyl)anthracene, bpea; and bpy = 4,42 -bipyridine) containing two different types of pyridyl ligands were synthesized, characterized and their photophysical properties studied. Successful emission color tuning was achieved by incorporating rigid alkynyl ligands into the Re(I… Show more

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