Synthesis and Physical Properties of Some C<sub>12</sub> and C<sub>13</sub> Phenylalkane and Cyclohexylalkane Hydrocarbons

Lamberti, J. M.; Wise, Paul H.

doi:10.1021/ja01115a050

Cited by 19 publications

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“…Doolittle and Peterson (S) prepared and studied a number of n-paraffins. Wise and associates {6, 7, 12,13,16,17,35) have reported over 100 pure hydrocarbons, mainly dicyclics in the CJ2 and CiS range. A research group directed by R. W. Schiessler and the late F. C. Whitmore has prepared {31, 32, 38-40) over 230 pure hydrocarbons, covering many molecular types and classes over the range C8 to C50, with the greatest concentration in the C2ii to C30 region.…”

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Properties of High Molecular Weight Hydrocarbons

Schiessler¹,

Whitmore²

1955

Ind. Eng. Chem.

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INTERPRETATIONof the effect of molecular constitution on the physical properties of pure substances has contributed greatly to man's understanding of the physical world, and has often permitted the segregation and evaluation of intraand intermolecular effects. Because of the variety of molecular structures possible, compounds of carbon have been especially useful in such investigations, and the compounds of carbon and hydrogen are usually taken as reference structures to which other carbon compounds are related. For these and other cogent reasons,

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confidence: 99%

Properties of High Molecular Weight Hydrocarbons

Schiessler¹,

Whitmore²

1955

Ind. Eng. Chem.

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Préparation de Styrènes α, β Disubstitués

Barbieux

Martin

1964

Bulletin des Soc Chimique

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The nitration of mono‐alkylbenzenes conformational analysis and steric hindrance: Part II: Secondary alkylbenzenes

Baas

Wepster

1971

Recl. Trav. Chim. Pays‐Bas

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The isomer distributions for the nitration of six srconclrrry alkylbenzenes and the partial rate factors of three of these compounds have been determined. The stei-ic hindrance of the nitration in the orrho-position of isopropylbenzene is mainly of an enthalpic nature. The increase of this hindrance in the series of isopropylbenzene, s-butylbenzene, ( I -ethylpropyl)benzene is of an entropic nature and can be explained from the conformational analysis u l the initial states and the transition states. The steric hindrance in the orrho-positions of (2-methyl-Iisopropy1propyI)benzene and (I-1-butyl-2.2-dirnethylpropy1)benzcne is very la rye.

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Synthesis and Physical Properties of Some C₁₂ and C₁₃ Phenylalkane and Cyclohexylalkane Hydrocarbons

Cited by 19 publications

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Properties of High Molecular Weight Hydrocarbons

Properties of High Molecular Weight Hydrocarbons

Préparation de Styrènes α, β Disubstitués

The nitration of mono‐alkylbenzenes conformational analysis and steric hindrance: Part II: Secondary alkylbenzenes

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Synthesis and Physical Properties of Some C12 and C13 Phenylalkane and Cyclohexylalkane Hydrocarbons

Cited by 19 publications

References 0 publications

Properties of High Molecular Weight Hydrocarbons

Properties of High Molecular Weight Hydrocarbons

Préparation de Styrènes α, β Disubstitués

The nitration of mono‐alkylbenzenes conformational analysis and steric hindrance: Part II: Secondary alkylbenzenes

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Product

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Synthesis and Physical Properties of Some C₁₂ and C₁₃ Phenylalkane and Cyclohexylalkane Hydrocarbons